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'yr Olefm Iridium Complexes' in keywords Facet   Publication Year 1982  [X]
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1Author    Jörn Müller, Wolfgang Hähnlein, Barbara PassonRequires cookie*
 Title    TT-Olefin-Iridium-Komplexe, IX [1] Bis(?y 4 -butadien)-(7-organyl-iridium-Verbindungen TI-Olefin Iridium Complexes, IX [1] Bis(fy 4 -butadiene)-cr-organyl-iridium Compounds  
 Abstract    Complexes of the type [L2IrR] (L = butadiene, isoprene, piperylene, 1,4-and 2,3-dimethylbutadiene; R = CH3, CeHs) have been synthesized by reactions of [L2IrCl] with LiR in hexane. With L = 2,3-dimethylbutadiene, [L2IrR] compounds with higher alkyl groups R (e.g. n-C3H7, n-CjHg) can be obtained which for steric reasons are inert against ^-elimination. Th© system [L2IrCl]/L/LiAlH4 (L = 2,3-dimethylbutadiene) yields [L2IrR] with R = 2,3-dimethylbutene-2-yl. The complexes were characterized by NMR and mass spectra. 
  Reference    Z. Naturforsch. 37b, 1573—1579 (1982); eingegangen am 8. Juli 1982 
  Published    1982 
  Keywords    Synthesis, Mass Spectra, NMR Spectra, yr-Olefm Iridium Complexes 
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 TEI-XML for    default:Reihe_B/37/ZNB-1982-37b-1573.pdf 
 Identifier    ZNB-1982-37b-1573 
 Volume    37