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'y Diondioxime Complexes' in keywords
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1982 (1)
1Author    Helmut Endres, Nasser Kadkhodai-ElyaderaniRequires cookie*
 Title    Malonenamidoxim, Nickelkomplexe und deren ßeaktionsprodukte mit Sauerstoff und Kohlendioxid: Vergleichende Strukturuntersuchungen Malonenamide Oxime, Nickel Complexes, and their Reaction Products with Oxygen and Carbon Dioxide: Comparative Structural Studies  
 Abstract    Malonenamide oxime [HONC(NH2)CH2C(NH2)NOH = C3H8N402] (1), its bis-chelate complex with Ni(II) [Ni(C3HyN402)2] (2) and an ethanol solvate of this complex [Ni(C3H7N402)2 • 0.6 C2H5OH] (3) are characterized by X-ray structure analysis, as well as a paramagnetic tris-complex [Ni(C3H7N402)2(C3HsN402)] (4), which forms a catena structure in the crystal. The molecular structures of two reaction products of 2 with air are described: [Ni(C3H5N403)2(H20)2] • 4 H20 (5) has formed by oxidation of the methylene groups and may be taken as a complex of mesoxalamide oxime; [NiCsHieNsOs] • 6 H20 (6) has a macrocyclic ligand which is a derivative of orthocarbonic acid, formed by addition of carbon dioxide to the oxime groups. 
  Reference    Z. Naturforsch. 37b, 1255—1265 (1982); eingegangen am 25. Mai 1982 
  Published    1982 
  Keywords    a, y-Diondioxime Complexes, Crystal Structure 
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 TEI-XML for    default:Reihe_B/37/ZNB-1982-37b-1255.pdf 
 Identifier    ZNB-1982-37b-1255 
 Volume    37