ZfN: Search Results

1	Author	Z. Naturforsch	Requires cookie*
	Title	Ag+ als Substituent eines Alkalimetalls in Ag2SrMnV20 8
	Abstract	Single crystals of Ag2 SrM nV20 8 have been prepared by reactions of metallic silver and a mixture of S rC 0 3, M nC 03 HoO and V ?0 5. X-Ray investigations showed monoclinic symmetry, space group Cfh-C2/c, a = 9.7022(9), b = 5.5882(5), c = 13.894(1), ß = 90.41(1)°, Z = 4. The crystal structure is isotypic to N a2BaCuV20 8 and includes V 0 4 tetrahedra, M n 0 6 octahedra as well as irregular A g 0 8 and S rO !0 polyhedra. Ag2SrM nV20 8 is characterized by a [MnV20 8] network incorporating Ag+ and S r + or a [Ag2V 2Ö 8] frame incorporating Mn2+ and Sr2+ ions. Ag+ is able to replace an alkali ion in the cationic part of the crystal structure.
	Reference	Z. Naturforsch. 53b, 279—282 (1998); eingegangen am 17. November 1997
	Published	1998
	Keywords	Silver, Strontium, Manganese, Vanadium Oxide
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	TEI-XML for	default:Reihe_B/53/ZNB-1998-53b-0279.pdf
	Identifier	ZNB-1998-53b-0279
	Volume	53

2	Author	Hk Wulff, Müller-Buschbaum	Requires cookie*
	Title	Isolierte trigonale S r 0 6-Prismen verknüpfen Kagome-Netze im Strontium-Manganat(I V)-Tellurat( VI): SrMnTe06 Kagome Layers Connected by Isolated Trigonal Sr06 Prisms in the Strontium Manganate(IV) Tellurate(VI): SrMnTe06 L
	Abstract	Single crystals of the hitherto unknown compound SrM nT e06 have been prepared from Sr(0H)2-8H20 , M n C 0 3(aq) and T e 0 2 in air by crystallization below the melt range. X-ray in vestigations showed hexagonal symmetry, space group D3h-P62m, lattice constants a = 5.143(1), c = 5.384(2) A, Z = 1. SrM nTe06 is characterized by staggered [(Mn/Te)60 18] Kagome layers along [001]. These layers are connected by Sr2+ ions, resulting in S r0 6 prisms isolated from each other. The structure is discussed with respect to the connection of Kagome nets in the quaternary oxides of the Ba3Ln40 9 type.
	Reference	Z. Naturforsch. 53b, 283—286 (1998); eingegangen am 7. November 1997
	Published	1998
	Keywords	Strontium, Manganese, Tellurate, Crystal Structure
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	TEI-XML for	default:Reihe_B/53/ZNB-1998-53b-0283.pdf
	Identifier	ZNB-1998-53b-0283
	Volume	53

3	Author	M. Ichael Schmidt, Annette Schier, Hubert Schmidbaur	Requires cookie*
	Title	Magnesium Bis[D(-)-Mandelate] Dihydrate and Other Alkaline Earth, Alkali, and Zinc Salts of Mandelic Acid
	Abstract	, and zinc D(-)mandelates have been prepared from the parent mandelic acid and equivalent quantities (1:1 / 2:1) of the corresponding metal hydroxides in water. Colourless polycrystalline products are obtained from the aqueous solutions by evaporation of the solvent. The alkali, ammonium and strontium salts are anhydrous, the calcium and barium salts are monohydrates, the magne sium salt is a dihydrate, and the zinc salt a trihydrate. The crystal and molecular structure of the magnesium salt has been determined by single crystal X-ray diffraction methods (mono clinic, space group P2i, Z = 2). The lattice contains isolated complexes with hexacoordinate magnesium atoms chelated by two mandelate anions through one of their carboxylate oxygen atoms and the alcoholic hydroxyl group. Two water molecules in cis position are completing the octahedral coordination sphere. [MgtQITO^MfTO^] is thus a true mononuclear magnesium complex. Its stability and non-hygroscopic properties suggest its use as a magnesium and/or mandelate drug.
	Reference	Z. Naturforsch. 53b, 1098—1102 (1998); received July 23 1998
	Published	1998
	Keywords	Mandelic Acid, Magnesium Mandelate, Alkaline Earth Mandelates, Alkali Mandelates, Zinc Mandelate Lithium, sodium, potassium, ammonium, magnesium, calcium, strontium, barium
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	TEI-XML for	default:Reihe_B/53/ZNB-1998-53b-1098.pdf
	Identifier	ZNB-1998-53b-1098
	Volume	53