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2001 (1)
1Author    Swathi Pisupati, P. A. Kumar, V.G K M PisipatiRequires cookie*
 Title    Induced Smectic-G Phase through Intermolecular Hydrogen Bonding Part IX: Comparative Thermal and Phase Behaviour Studies on Two Distinct Structural Isomers Possessing Linear and Bow Shapes  
 Abstract    Two novel intermolecular hydrogen bonding mesogenic series comprising two distinct structural iso­ mers nABA:R:nABA and «ABA:H:«ABA (where R = resorcinol; H = hydroquinone; nABA = p-n-al-kyloxybenzoic acid with the alkyl carbon number varying from propyl-to decyl-and dodecyl-) have been synthesized using resorcinol and hydroquinone as central bent and linear cores, respectively. The thermal and phase behaviour of these complexes is studied by thermal microscopy and differential scan­ ning calorimetry. The IR spectral data confirm the formation of intermolecular hydrogen bonding between the OH group of the non-mesogen and -COOH group of the nABA moiety. Thermal studies reveal the existence of new phases: smectic-A and smectic-G. Comparative phase transition studies sug­ gest that these isomers exhibit a different trend of mesomorphism. 
  Reference    Z. Naturforsch. 56a, 692—696 (2001); received July 4 2001 
  Published    2001 
  Keywords    Hydrogen Bonding, Thermal, Phase Behaviour, rtABA:R:rcABA, nABA:H:rcABA 
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 TEI-XML for    default:Reihe_A/56/ZNA-2001-56a-0692.pdf 
 Identifier    ZNA-2001-56a-0692 
 Volume    56