| | 1 | Author
| Jürgen Schatz3, Frank Schildbacha, AxelL. | Requires cookie* | | | Title
| The Inclusion of Carbon Disulfide in /?-rerf-Butylcalix[4]-and [6 ]arene - A Combined Crystallographic and Vibrational Spectroscopic Study  | | | | Abstract
| en tzb, Sylvia R a stä tte rb, Joachim Schilling5, Jö rg D o rm an n c, A n d reas R uoffc, and Tony D eb ae rd em ae k erd The inclusion complexes formed from carbon disulfide and /?-r£7-r-butylcalix[4]arene (1 C S 2) or /?-rm-butylcalix[6]arene (2-C S2) were investigated by X-ray crystal structure analysis, infrared (IR) and Raman spectroscopy. The complex 1 C S 2 crystallises in the space group P4/n, 2 C S 2 in the space group P2xln. In case of /?-rm-butylcalix[4]arene as host the carbon disulfide molecule is included in the cavity. In the crystal structure of p-rm -butylcali-x[6]arene clathrate, self-com plexation o f one rm-butyl group in the cavity o f another ca-lix[6]arene can be observed. Due to inclusion, the symmetry of CS2 is lowered both in the p-rm -butylcalix[4]arene and p-rm-butylcalix[6]arene case causing significant shifts in the fully assigned infrared and Raman spectra. | | | |
Reference
| Z. Naturforsch. 55b, 213—221 (2000); received N ovem ber 16. 1999 | | | |
Published
| 2000 | | | |
Keywords
| p-rerz-Butylcalixarenes, Inclusion Complexes, Crystal Structure, IR Data, Raman Data | | | |
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| default:Reihe_B/55/ZNB-2000-55b-0213.pdf | | | | Identifier
| ZNB-2000-55b-0213 | | | | Volume
| 55 | |
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