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'normal coordinate analysis' in keywords Facet   Publication Year 1994  [X]
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1Author    Bromo, P. Prillwitz, W. PreetzRequires cookie*
 Title    Darstellung, Schwingungsspektren und Normalkoordinatenanalyse der  
 Abstract    The IR and Raman spectra of the ten brom o-iodo-rhenates(IV) [ReBr"I6_"]2 -, n = 0 -6 , including the geometrical isomers for n -2,3,4, have been recorded at 80 K. The vibrational spectra are com pletely assigned according to point groups O h, D 4h, C4v, C3v, and C2v, as supported by normal coordinate analyses based on a general valence force field. Due to the different mms-influences Br < I in asymmetric axes B r '-R e -I ', the R e -I ' bonds are strengthened and the R e -B r ' bonds are weakened, as indicated by valence force constants, for R e -I ' on average 8,5% higher and for O s -B r ' 8,3% lower, as compared with the values calculated for symmetric I -R e -I and B r -R e -B r axes, respectively 
  Reference    Z. Naturforsch. 49b, 753—7 (1994); eingegangen am 7. März 1994 
  Published    1994 
  Keywords    -Iodo-Rhenate(IV), [ReBr, !^, ]2-, n = 0 -6 Brom o-Iodo-Rhenates(IV ), Stereoisomers, rra/is-Influence, Vibrational Spectra, Normal Coordinate Analysis 
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 TEI-XML for    default:Reihe_B/49/ZNB-1994-49b-0753.pdf 
 Identifier    ZNB-1994-49b-0753 
 Volume    49