| | 1 | Author
| Karl Wieghardt, Ursula Bossek, Martina Guttmann, Johannes Weiss | Requires cookie* | | | Title
| Metallkomplexe der Liganden  | | | | Abstract
| 1.4.7-Triazacyclononan-N.N .N -tris-2-ethansulfonat (TES) und 1.4.7-Triazacyclononan-N.N' .N'' -trisethylacetat (TEA). Die Kristallstrukturen von Na[Ni(TES)(H20)] • 5 H20 und Na[Cu(TES)] • 3 H20 Transition Metal Complexes Containing the Ligands 1,4,7-Triazacyclononane-N,N',N"-tris-2-ethanesulfonate (TES) and l,4,7-Triazacyclononane-N,N , ,N"-tris-ethylacetate (TEA). The Crystal Structures of Na[Ni(TES) (H20)] • 5H20 and of Na[Cu(TES)] • 3H20 The syntheses of two new, potentially hexadentate ligands with an N3O3 donor set is reported: l,4,7-triazacyclononane-N,N , ,N"-tris-2-ethanesulfonate (TES) and 1,4,7-tria-zacyclononane-N,N',N"-tris-ethylacetate (TEA). Complexes of the divalent transition metals Co(II), Ni(II), Cu(II) containing these ligands have been prepared. The kinetics of the reactions of [Co n (TEA)H20] 2 + and [Co II (TCTA)]-(TCTA= 1,4,7-triazacyclononane-N^^N'^tris-acetate) with [Fe m (CN)6] 3 ~, respectively, have been measured. A stable binuclear [Co(TEA)(CN)6Fe]~ species has been characterized in solution whereas the reaction of [Co(TCTA)]-with [Fe(CN)6] 3 -yields [Co in TCTA] and [Fe(CN)6] 4 -via an outer-sphere electron transfer reaction (k = 5,9 x 10 3 1 mol -1 sec -1 ; 25 °C, I = 0,26 M). Na[Ni(TES)H20] • 5H20 crystallizes in the triclinic space group P I (C^-No 2) with cell constants a = 806,7(4), b = 1468,4(8), c = 2317,9(8) pm, a = 72,36(4)°, ß = 83,48 (3)°, y = 81,99(4)°, and Z = 4. The nickel(II) center is in a distorted octahedral environment of a pentadentate TES ligand (N3Ü2)_and a coordinated H20. Na[Cu(TES)] 3H20 crystal-lizes in the triclinic space group P I (C^-No 2) w T ith cell constants a = 747,3(3), b — 1082,6(5), c = 1459,3(9) pm, a = 81,13(5)°, ß = 84,75(4)°, y = 79,39(3)°, and Z = 2. The copper(II) center is in a distorted quadratic pyramidal environment of a pentadentate TES ligand. Each of the complex anions contains one uncomplexed CH2-CH2-SC>3 _ group. | | | |
Reference
| (Z. Naturforsch. 38b, 81—89 [1983]; eingegangen am 27. September 1982) | | | |
Published
| 1983 | | | |
Keywords
| Crystal Structure, O-Coordinated R-S03-group, Metal Complexes | | | |
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| default:Reihe_B/38/ZNB-1983-38b-0081.pdf | | | | Identifier
| ZNB-1983-38b-0081 | | | | Volume
| 38 | |
| 2 | Author
| H. W. Roesky, D. Amirzadeh-Asl | Requires cookie* | | | Title
| Preparation and Reactions of Bicyclic Compounds with a Phosphorus-Phosphorus-Bond | | | | Abstract
| The reaction of N,N'-dimethyl-N,N'-bis(trimethylsilyl)urea with PCI3 leads to the bicyclic compound OP2[MeNCONMe]2 (3) with a direct phosphorus-phosphorus bond and to the bicycle MeNP2[MeNCONMe]2 (4). 3 reacts with tetrachloro-o-benzoquinone (TOB) to yield the spirocycle CeCl^tMeNCONMe^PaO (5) with a A 4 P-A 5 P-bond. The Lewis acids SbCls and SnCLj react with 3 to give the adducts 6 and 7. The reactions of 3 with the metal carbonyls Fe2(CO)9, Cr(CO)5THF and Cr(CO)4C7Hx lead to the metal complexes 8-10. The compounds were characterized on the basis of 31 P NMR and mass spectra. Kürzlich haben wir gezeigt, daß Reaktionen von disilylierten Harnstoffen mit Dichlorphosphanen, | | | |
Reference
| Z. Naturforsch. 38b, 460—464 (1983); eingegangen am 14. Dezember 1982/27. Januar 1983 | | | |
Published
| 1983 | | | |
Keywords
| 31 P NMR, Metal Complexes, Oxidative Addition | | | |
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| default:Reihe_B/38/ZNB-1983-38b-0460.pdf | | | | Identifier
| ZNB-1983-38b-0460 | | | | Volume
| 38 | |
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