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'metal complexes' in keywords Facet   Publication Year 1978  [X]
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1Author    Thomas Krück, Werner Thielmann, Christian SauerRequires cookie*
 Title    Metallkomplexe mit anionischen Liganden von Elementen der 4. Hauptgruppe, XI [1] Homogene Trichlorstannidometallat(O)-Komplexe der 6. und 8. Nebengruppe Metal Complexes with Anionic Ligands of Elements of the Main Group IV, XI [1] Homogenous Trichlorostannido Metalate(O) Complexes of the Transition Groups VI and VIII  
 Abstract    Various homogeneous metalate(O) complexes are synthesized with [SnCl3] -as a ligand. Complexes of the type [M(SnCl3)6] 6 -are prepared from [M(CO)3(SnCl3)3] 3 -(M = Cr, Mo, W) in nitromethane. [Fe(SnCl3)5] 5_ is formed by UV irradiation of [Fe(CO)4SnCl3]~ in aceto-nitrile. [M(SnCl3)4] 4-(M = Ni, Pd, Pt) anions are synthesized by thermal substitution reactions with Ni(CO)4, Pd(PF3)4, and Pt(PF3)4. All metalate(O) ions are isolated as salts with the [N(C2H5)4] + cation and characterized by IR spectra and 119m Sn-Mössbauer spectra as well as by analysis. 
  Reference    Z. Naturforsch. 33b, 1291—1295 (1978); eingegangen am 12. Juli 1978 
  Published    1978 
  Keywords    Synthesis, FIR Spectra, 119m Sn-Mössbauer Spectra, Metal Complexes, Anionic Ligands 
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 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-1291.pdf 
 Identifier    ZNB-1978-33b-1291 
 Volume    33