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1997[X]
1Author    R. Rettich, Hk Müller-BuschbaumRequires cookie*
 Title    Isolierte MnCl6-Oktaeder im Oxohalogeno-Vanadat Ba5(Mg0,4Mn0,6)(V2O7)2MnCl6 Isolated MnCl6 Octahedra in the Oxohalogeno Vanadate Ba5(M g0 4Mn0 6)(V20 7)2MnCl6  
 Abstract    Single crystals o f Ba5(M g0 4Mn0 6)(V20 7)2MnCl6 have been prepared by solid state reactions of M g C 0 3, Mn20 3, V20<i and BaCl2 -2H20 below the melting point of BaCl2. The new vanadium oxide chloride crystallizesowith monoclinic symmetry, space group C2h-P2/c, a = 13.345(4), b = 5.711(2), c = 15.859(4) Ä, ß = 113.69(2)°, Z = 2. Special features of the crystal structure are isolated MnCl6 octahedra and layers created by divanadat groups and (M g,M n)06 octahedra. The ^ [(Mg,Mn)V20 7] nets of Ba5(Mg0 4Mn0 6)(V20 7)2MnCl6 are discussed with respect to other oxohalogeno vanadates containing divanadate groups. 
  Reference    Z. Naturforsch. 52b, 457—461 (1997); eingegangen am 15. Januar 1997 
  Published    1997 
  Keywords    Barium, Magnesium, Manganese, Chlorine, Vanadium Oxide 
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 TEI-XML for    default:Reihe_B/52/ZNB-1997-52b-0457.pdf 
 Identifier    ZNB-1997-52b-0457 
 Volume    52