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1979 (1)
1Author    U. '. Tifat, R. Lyatifov, StanislavP. Solodovnikov, ValeryN. Babin, RosaB. MaterikovaRequires cookie*
 Title    Salts of Ferricinium Cation and its Homologues: NMR Investigation, I On Mechanisms of Spin Derealization in Salts of Ferricinium and l,l'-Dimethylferricinium Cation  
 Abstract    X H and 13 C NMR spectra of hexafluorophosphates of ferricinium (1) and 1,1'-dimethyl -ferricinium cations (2) and the EPR spectrum of 2 were recorded. Pseudocontact and contact contributions of isotropic shift were calculated and constants of hyperfine inter-action estimated according to Jesson. It is shown that the calculations of pseudocontact and contact shift via magnetic susceptibility components according to Kurland and McGarvey do not change the signs of HFS constants. According to the suggested mecha-nisms of spin derealization the jz-contribution is the dominating one. 
  Reference    Z. Naturforsch. 34b, 863—866 (1979); received October 10 1978/January 23 1979 
  Published    1979 
  Keywords    Ferricinium, l, l'-Dimethylferricinium, Spin Derealization, NMR 
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 TEI-XML for    default:Reihe_B/34/ZNB-1979-34b-0863.pdf 
 Identifier    ZNB-1979-34b-0863 
 Volume    34