| | 3 | Author
| Herrn, Dr, Dr | Requires cookie* | | | Title
| Transanulare Wechselwirkung bei  | | | | Abstract
| [m.n]Phanen, 32 [1]: Modelle für Amin-Aromaten-Exciplexe: [2](l,4)Anthraceno[2](2,6)pyridinophan-l,13-dien Transanular Interaction in [m .n]Phanes, 32 [1 ]: Models for Am ine-A rene-Exciplexes: [2](l,4)A nthraceno[2](2,6)pyridinophan-l,13-dien M atthias W. H a e n e l* 3, Birgit L intnera und D ieter Schweitzer11 a M ax-Planck-Institut für K ohlenforschung, Kaiser-W ilhelm -Platz 1, D-4330 M ülheim a .d . Ruhr b M ax-Planck-Institut für M edizinische Forschung, A bteilung M olekulare Physik, Jahnstraße 29, D -6900 H eidelberg The [2](1.4)A nthracen o[2](2,6)pyridinop han-l,13-d ien (5) and the corresponding [2.2]phane (7) were synthesized as m odels for exciplexes. The dithia[3.3]phanes (9) and (11) were prepared by cyclisation o f the dithiols 13 and 16 with the dibrom ide 19. O xidation of 9 to the disulfone 10 and vapour phase pyrolysis led to 7. Ring contraction o f 9 by S-analogous Wittig ether rearrange ment led to 20 which was converted to the diene 5 via oxidation to the disulfoxide 21 and pyrolytic elim ination o f m ethane sulfenic acid. A ttem pts to prepare 6 and 8 via similar routes from 11 failed. Electron absorption spectra and fluorescence spectra o f 5 and 7 are discussed in terms of n-n interaction in 5 and jt-jt interaction in 7. | | | |
Reference
| Z. Naturforsch. 41b, 223 (1986); eingegangen am 7. Oktober 1985 | | | |
Published
| 1986 | | | |
Keywords
| Cyclophanes, Electronic Interaction, Exciplex M odels U V Spectra, Fluorescence | | | |
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| default:Reihe_B/41/ZNB-1986-41b-0223.pdf | | | | Identifier
| ZNB-1986-41b-0223 | | | | Volume
| 41 | |
| 5 | Author
| G. C. Papavassiliou, G. A. Mousdis, I. B. Koutselas | Requires cookie* | | | Title
| Some Organic-Inorganic Hybrid Compounds Based on «ö-Thiuronium Cations and Lead Halide Anions | | | | Abstract
| Using 1-chlorodecane (C10H21CI), benzyl chloride (C6H5CH2CI), a,a'-dichloro-p-xylene (CICH2C6H4CH2CI), 4-phenylbenzyl chloride (C6H5C6H4CH2CI), 2-bromomethyl-naphthal-ene (CioHyC^Br), 4-bromomethyl-7-methoxycoumarin (CioHzO^C^Br), 2-bromomethyl-anthraquinone (CuH TC ^C ^Br), 9-chloromethyl-anthracene (C14H9CH2CI), thiourea and halides as starting materials, the organic-inorganic hybrid compounds [CioH2iSC(NH2)2]2Pbl4, [C6H5CH2SC(NH2)2]4Pb3l,o, [(H sN h C S C ^ C ö H tC ^ S Q N H jh k sP b ls, [C6H5C6H4CH2S-C(NH2)2]PbI3, [C,oH7CH2SC(NH2)2]Pbl3, [CioH yChC^SQNHzhlPbL, [C^HyOjCHzSC-(NH2)2]PbI3, [C,4H9CH2SC(NH2)2]Pbl3, and [C M H gO ^SQ N H z^hPbB ^ were prepared and characterized analytically and spectroscopically. | | | |
Reference
| (Z. Naturforsch. 56b, 57—61 [2001]; received September 11 2000) | | | |
Published
| 2001 | | | |
Keywords
| Organic-Inorganic Hybrids, Low-Dimensional Semiconductors, Fluorescence | | | |
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| default:Reihe_B/56/ZNB-2001-56b-0057.pdf | | | | Identifier
| ZNB-2001-56b-0057 | | | | Volume
| 56 | |
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