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41	Author	St Gallinat, Hk Müller-Buschbaum	Requires cookie*
	Title	Two Examples of Partial and Total Defects in the B a«Ln2Mo4O i6-Type: BaCu0 41 ■o,59Pr2Mo4 0 16 and BaBYb2Mo4Ojg
	Abstract	Single crystals of (I) BaCu0.4iPr2M o4O 16 and (II) BaYb2M o40 16 have been prepared by flux technique. Both compounds crystallize with m onoclinic symmetry, space group C2h-C 2 /c with (I): a = 5.352(11), b = 12.888(2), c = 19.399(4) A; ß = 90.89(3)°; (II): a = 5.181(7), b = 12.467(3), c -19.350(3) Ä , ß -91.93(2)°, Z = 4. The crystal structure is characterized by i [ B a M 0 12]-chains along [010]. In the first case the M positions are occupied by copper by about 41%, in the second case these positions remain com pletely unoccupied. With respect to the crystal chemistry of the reference compound Ba(Cu0.22Mg() 78)Nd2Mo4O 16 all substan ces of the composition BaLn2M o40 16 should be written as Ba»Ln2Mo40 16 indicating the holes in th e^ B a M O i^ -c h a in s by ■.
	Reference	(Z. Naturforsch. 51b, 85—8 [1996]; eingegangen am 7. Juni 1995)
	Published	1996
	Keywords	Barium, Copper, Rare Earth, Molybdenum Oxide, Crystal Structure
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0085.pdf
	Identifier	ZNB-1996-51b-0085
	Volume	51

42	Author	O. Sedello, Hk Müller-Buschbaum	Requires cookie*
	Title	Ein Oxometallat mit eindimensional flächenverknüpften Oktaederketten Synthesis and Crystal Structure of (C u,Fe)363M o3O i2. An Oxom etallate Showing One-Dimensional Chains of Face Sharing Octahedra
	Abstract	Single crystals of (C u ,F e)3-63M o30 12 have been prepared by crystallisation from melts. X-ray investigations lead to orthorhombic symmetry, space group D : 2-P 2 12121, a = 5.0952(8), b = 10.637(2), c = 17.881(3) A , Z = 4. (C u ,F e)363M o3O i2 is isotypic to Cu385M o30 12 or (C u,Z n)3 75M o30 12. M olybdenum shows tetrahedral coordination by oxygen. Cu+ and Fe2+ are probably distributed statistically over four different point positions. Interesting features of the crystal structure are one-dim ensional chains of face shared (C u ,F e)0 6 octahedra. S y n t h e s e u n d K r i s t a l l s t r u k t u r v o n (C u , F e) 3 ,63 M o 3 0 12.
	Reference	(Z. Naturforsch. 51b, 90—9 [1996]; eingegangen am 20. Juni 1995)
	Published	1996
	Keywords	Copper, Iron, M olybdenum, Oxide, Crystal Structure
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0090.pdf
	Identifier	ZNB-1996-51b-0090
	Volume	51

43	Author	Hk Müller-Buschbaum, St Gallinat	Requires cookie*
	Title	Zur Kristallchemie von CuDyMo20 8 und CuYbMo20 8 On the Crystal Chemistry o f C uD yM o20 8 and CuYbM o2O g
	Abstract	Single crystals o f (I) C uD yM o20 8 and (II) CuYbM o20 8 have been prepared by crystalli sation from melts. Both com pounds crystallize with orthorhombic symmetry, space group D 2 5h~Pbca with (I): a = 10.195(1), b = 9.721(2), c = 14.563(3); (II): a = 10.094(6), b = 9.628(9), c = 14.467(8) A , Z = 8. The crystal structure is characterized by a triangular C u 0 3-polygon, a square antiprismatic coordination around the Rare Earth ions and the typical M o 0 4 tetra hedra.
	Reference	Z. Naturforsch. 51b, 240 (1996); eingegangen am 18. Mai 1995
	Published	1996
	Keywords	Copper, Rare Earth M olybdenum Oxide, Crystal Structure
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0240.pdf
	Identifier	ZNB-1996-51b-0240
	Volume	51

44	Author	O. Sedello, Hk Müller-Buschbaum	Requires cookie*
	Title	On the Crystal Structure o f (C u ,M n )3 66M o30 12
	Abstract	Single crystals o f (Cu,M n)3 66M o 30 12 have been prepared in sealed copper tubes. X-ray investiga tions lead to orthorhombic symmetry, space group Dih-Pnm a, a = 5.1541(9), b = 10.788(2), c = 18.114(3)) Ä , Z = 4. (Cu,M n)366M o 30 12 is iso typic to NaCo2 31M o 30 12 and (C u,C o)3 75M o 30 12 with split positions for two o f the metals.
	Reference	Z. Naturforsch. 51b, 447—449 (1996); eingegangen am 31. August 1995
	Published	1996
	Keywords	Copper, Manganese, Molybdenum Oxide, Crystal Structure
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0447_n.pdf
	Identifier	ZNB-1996-51b-0447_n
	Volume	51

45	Author	O. Sedello, Hk Müller-Buschbaum	Requires cookie*
	Title	On the Crystal Structure of (Cu, M n )U M o 30 12
	Abstract	Single crystals of (C u,M n)U M o30 12 have been prepared in sealed copper tubes. X-ray investiga tions lead to hexagonal symmetry, space group C\|h-P63/m, a = 9.7895 (13), c = 6.202(1) A , z = 2. (C u ,M n)U M o30 12 is isotypic to CdThM o30 12. Calculations of the Coulomb terms o f lattice energy with respect to different oxidation states o f copper, molybdenum and uranium and the pre viously described pair of isotypic compounds of CdThM o30 12 to Na2ThRe60 24 are discussed.
	Reference	Z. Naturforsch. 51b, 450—452 (1996); eingegangen am 5. September 1995
	Published	1996
	Keywords	Copper, Manganese, Uranium Molybdenum Oxide, Crystal Structure
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0450_n.pdf
	Identifier	ZNB-1996-51b-0450_n
	Volume	51

46	Author	Hk Sedello, Müller-Buschbaum	Requires cookie*
	Title	O
	Abstract	Single crystals of BaCuTe03T e 0 4 have been prepared by crystallisation from melts. X-ray investigations lead to orthorhombic symmetry, space group C2v-Ama2, a = 5.4869(8), b = 15.412(1), c = 7.2066(4) A , Z = 4. This compound represents a new structure type, containing B aO 10, C u 0 5, T e 0 6 and T e 0 4 polyhedra. The lone pair (E) of TeIV completes the TeIV0 4 polyhedron to a trigonal T e 0 4E bipyramid. The Te to E distance is estimated by calculations o f the Coulomb terms of lattice energy to 1.43 A .
	Reference	Z. Naturforsch. 51b, 465—468 (1996); eingegangen am 31. August 1995
	Published	1996
	Keywords	Barium, Copper, Tellurium, Oxide, Crystal Structure
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0465.pdf
	Identifier	ZNB-1996-51b-0465
	Volume	51

47	Author	V-	Requires cookie*
	Title	Zwei monokline Kupfer-Oxovanadate des Magnesiums mit geordneter Metallverteilung: /w-Mg2CuV20 8 und MgCu2V20 8. Ein Beitrag zur Dimorphie von Mg2CuV2Os Two Monoclinic Copper Oxovanadates of Magnesium Showing Ordered Metal Distribution: m-Mg9CuV-,08 and MgCu
	Abstract	Single crystals of ra-Mg2CuV20 8 (I) and MgCu2V20 8 (II) have been prepared by solid state reactions. The orange (I) and dark red (II) crystals show monoclinic symmetry, space group C2h -P2,/c, (I): a = 6.167(3), b = 8.172(5), c = 6.400(8) Ä, ß = 116.22(3)°, Z = 2; (II): a = 6.453(1), b = 8.342(2), c = 11.517(2) Ä, ß = 90.44(2), Z = 4. Both compounds show ordered metal distributions and vanadium in tetrahedral coordination by oxygen. (I) is characterized by elongated C u06 octahedra and (II) by trigonal C u 0 5 bipyramids. ra-Mg2CuV20 8 is the low temperature form of the formerly investigated orthorhombic o-Mg2CuV2Ö8. Calculations of the Coulomb parts of the lattice energy of the two crystal forms are discussed.
	Reference	Z. Naturforsch. 51b, 817—821 (1996); eingegangen am 4. Dezember 1995
	Published	1996
	Keywords	Magnesium, Copper, Vanadium Oxide, Crystal Structure
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0817.pdf
	Identifier	ZNB-1996-51b-0817
	Volume	51

48	Author	Z. Naturforsch	Requires cookie*
	Title	Über ein Blei-Kupfer-Tellurat PbC^TeOy mit Cu2+ in deformiert tetragonal pyramidaler und tetraedrischer Sauerstoffkoordination
	Abstract	On a Lead C opper Tellurate P b C u 3T e 0 7 Containing C u2+ in D istorted Square Pyram idal and Tetrahedral O xygen C oordination B. W edel, Hk. M üller-B uschbaum * PbCu3T e07 has been prepared from the element oxides by solid state reaction in air. Single crystal X-ray work led too orthorhombic symmetry, space group D^-Pnma, a = 10.488(1), b = 6.353(2), c = 8.813(2) A, Z = 4. Cu(1)0 5 square pyramids and Te06 octahedra are members of the anionic part of the crystal structure, Cu(2) atoms show tetrahedral coordination by oxygen. The C u (2)2+ and the Pb2+ cations are incorporated into a [Cu(l)2Te07] network. PbCu,Te07 can thus be viewed as a lead copper oxocuprate(II) tellurate. Calculations of the Coulomb terms of lattice energy reveal two possible positions for the lone pair of electrons at Pb'+.
	Reference	Z. Naturforsch. 51b, 1587—1590 (1996); eingegangen am 21. Mai 1996
	Published	1996
	Keywords	Lead, Copper, Tellurium, Oxide, Crystal Structure
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-1587.pdf
	Identifier	ZNB-1996-51b-1587
	Volume	51

49	Author	Hk Wulff, Müller-Buschbaum	Requires cookie*
	Title	Planare C u 0 4-Polygone und eine einseitig offene Te4+0 3-Koordination in SrCuTe20 6 Planar C u 0 4 Polygons and a One-Sided Open Te4+0 3 Coordination in SrCuTe-,06 L
	Abstract	The new compound SrCuTe20 6 has been prepared by quenching single crystals grown from a flux of SrC 03, T e02 and C uC 03 C u(0H)2. X-ray investigations show cubic symmetry, space group 0 7-P4\| 32, lattice constant a = 12.473(1), Z = 12. The crystal structure is characterized by square planar C u 0 4 polygons and a one-sided open triangular oxygen coordination of Te4+, both incorporated in a Sr/O network. The one sided oxygen coordination of tellurium is completed by the lone pair of Te4+. Calculations of the Coulomb parts of lattice energy led to the position of the lone pair centre.
	Reference	Z. Naturforsch. 52b, 1341—1344 (1997); eingegangen am 26. August 1997
	Published	1997
	Keywords	Strontium, Copper, Tellurium Oxide, Crystal Structure
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	TEI-XML for	default:Reihe_B/52/ZNB-1997-52b-1341.pdf
	Identifier	ZNB-1997-52b-1341
	Volume	52

50	Author	Andre Wiesch3, Hauke Timmb, Karsten Bluhm3	Requires cookie*
	Title	Uber CuDy2[B80 16] und CuHo2[B80 16]: Zwei neue "Metaborate" mit einem ^ [B80 16]g_-Anion On CuDy2[B80 16] and CuHo2[B80 16]: Two New "Metaborates" with a ^ [B80 16]8-Anion
	Abstract	Nearly colourless single crystals of the compounds CuDy2 [B80 i 6] (I) and CuHo2[B80)6] (II) have been obtained by a B20 3 flux technique. They crystallize in the structure of CuTb2 [B80)6] (I) or in an orthorhombic variant (II). X-ray investigations on single crystals led to the space group C2h -P2!/c (Nr. 14) with lattice parameters a = 1025,5(10); b = 836,99(10); c = 621,2(8) pm, ß = 90.47(10)°; Z = 2 (I) and D^h -Pbam (Nr. 55) with a = 840,7(2), b = 616,6(2), c = 1022,0(2) pm, Z = 2 (II). The structures contain 1 [B80 16]8_ chains isolated from each other, which include tri-and tetracoordinated boron, T'fie chains consist of alternating twelve and eight-membered rings of boron and oxygen atoms connected by B 0 4 units. Dy,+ and H o 3+ are octacoordinated and Cu2+ is hexacoordinated in elongated octahedra by oxygen. The relation between these two structures is discussed.
	Reference	(Z. Naturforsch. 53b, 1—4 [1998]; eingegangen am 23. Oktober 1997)
	Published	1998
	Keywords	Copper, Lanthanoids, Borate, Synthesis, Crystal Structure
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	TEI-XML for	default:Reihe_B/53/ZNB-1998-53b-0001.pdf
	Identifier	ZNB-1998-53b-0001
	Volume	53

51	Author	Lanthanoid Borates, A. Wiesch, K. Bluhm	Requires cookie*
	Title	CuHo2[B20 5]2* Ein unerwarteter Strukturtyp in der Reihe der Kupferlanthanoidborate CuHo2[B20 5]2: An Unexpected Structure Type in the Series of Copper
	Abstract	Single crystals of the new compound CuHo2 [B20 5 ]2 were obtained by using a B20 3 flux technique with CuO and Ho20 3 at 1050 °C. X-ray investigations on single crystals led to the space group P 2,/c (Nr. 14) with lattice parameters a = 454.3(2); b = 726.0(4); c = 936.0(5) pm; ß = 90.77(1)°; Z = 2. The compound is isotypic to CuTb2[B20 5 ] 2 as well as to the gadolinite structure (FeY2 [BeSi05]2). The structure exhibits layer-like 2 [B20 5]4~, a two-dimensional anion consisting of edge sharing B 0 4 -tetrahedra, which form four-and eight-membered rings. The layers are connected by elongated C u06-octahedra and slightly distorted tetragonal LnOs-antiprisms.
	Reference	(Z. Naturforsch. 53b, 5—8 [1998]; eingegangen am 23. Oktober 1997)
	Published	1998
	Keywords	Copper, Holmium, Borate, Synthesis, Crystal Structure
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	TEI-XML for	default:Reihe_B/53/ZNB-1998-53b-0005.pdf
	Identifier	ZNB-1998-53b-0005
	Volume	53

52	Author	Hk Wulff, Müller-Buschbaum	Requires cookie*
	Title	Zur Kristallchemie der Kupfer(II)-ZinkteIlurate Cu5 Zn4Te3 0 18
	Abstract	Cuj^Znj^TeOg, mit einer Notiz über Cul95Co1?5T e06 On the Crystal Chemistry of the Copper(II) Zinc Tellurates Cu5Zn4Te30 ,8 and Cu, 5Zn, 5Te06 with a Note on Cu, 5Co, 5Te06 L. Single crystals of Cu5Zn4Te30 , 8 (I), Cu, 5Zn, 5Te06 (II) and Cu, 5Co, 5Te06 (III) have been prepared and investigated by X-ray work. The structure of (I) was solved in the monoclinic space group C^-C2, a = 14.834(2), b = 8.801(1), c = 10.375(2) Ä, ß = 93.27(2)°, Z = 4. (II) and (III) crystallize with cubic symmetry, space group Th-Ia3, a{U) = 9.557(1), a(III) = 9.570(1) Ä, Z = 8. (I) shows a complicated structure formed by Te06 octahedra isolated from each other, Zn20 6 double tetrahedra and Zn20 8 double square pyramids. These polyhedra are incorporated into a network of edge and corner connected stretched C u06 octahedra. (II) and (III) are isotypic to Cu3T e06 and have a (Cu/M)30 6 octahedra network, statistically occupied by Cu2+ and Zn2+ or Cu_+ and Co2+.
	Reference	(Z. Naturforsch. 53b, 53—57 [1998]; eingegangen am 27. Oktober 1997)
	Published	1998
	Keywords	Copper, Zinc, Cobalt, Tellurate, Crystal Structure
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	TEI-XML for	default:Reihe_B/53/ZNB-1998-53b-0053.pdf
	Identifier	ZNB-1998-53b-0053
	Volume	53

53	Author	S. Meyer, Hk Müller-Buschbaum	Requires cookie*
	Title	Zur Kenntnis eines Vanadyl-Oxocuprat-Phosphats CaCu
	Abstract	(V0)(P0 4) 2 mit Cu2+ auf Positionen der V 0 2+-Ionen und einer kupferreicheren Phase CaCulvt3(VO)o,87(P04)2 On an Vanadyl Oxocuprate Phosphate C aC u(V 0)(P 04)2 Containing Cu2+ at Positions of V 0 2+ Ions and a Copper Rich Phase CaCu, !3(VO)0 g7(P04)2 Single crystals of CaCu(V 0)(P04)2 (I) and CaCu,.i3(VO)o.87(P04)2 (II) have been prepared using solid state reactions in closed and evacuated quartz tubes. X-ray characterization led to
	Reference	Z. Naturforsch. 53b, 521—526 (1998); eingegangen am 4. Februar 1998
	Published	1998
	Keywords	Calcium, Copper, Vanadyl-Phosphate, Crystal Structure
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	TEI-XML for	default:Reihe_B/53/ZNB-1998-53b-0521.pdf
	Identifier	ZNB-1998-53b-0521
	Volume	53

54	Author	Markus Tampier, Dirk Johrendt	Requires cookie*
	Title	B aC u 6G e2S8 -Ein Thiogermanat als Variante der L i3Bi-Struktur BaCu6Ge2S8 -A Thiogermanate as a Variant of the Li3Bi Structure
	Abstract	BaCu6Ge2S8 was synthesized by direct reaction of the elements at 750°C and characteri zed by X-ray single crystal techniques. The thiogermanate crystallizes in a new orthorhombic structure type (a = 6.122(1) A, b = 12.084(3) A , c = 17.614(5) A; Pbcm, Z = 4). Isola ted [GeS4]4_ tetrahedra form a slightly distorted cubic face-centered (fee) arrangement. Ba-and Cu-atoms each occupy half the octahedral gaps (O G) of this " tetrahedra packing" . Fur ther Cu atoms fill the tetrahedral gaps (T G) completely. The compound can be written as Ba2<l/2 0 G,(Cu2)2<l/2<:)G)Cu8<7G)(GeS4)4 . Thus the structure o f BaCu6Ge2S8 can be derived from the Li^Bi type. The sulfur coordination o f the metal atoms (Cu tetrahedral or trigonal, Ba with CN 8) are realized by the spatial orientation of the [GeS4]4~ tetrahedra. Their centers nearly maintain the fcc-arrangement. This structure interpretation of BaCu6 Ge2S8 from the viewpoint o f a " filled tetrahedra packing" is discussed for further known thiogermanate compounds.
	Reference	Z. Naturforsch. 53b, 1483—1488 (1998); eingegangen am 9. Juli 1998
	Published	1998
	Keywords	Chalcogenides, Germanium, Copper, Preparation, Crystal Structure
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	TEI-XML for	default:Reihe_B/53/ZNB-1998-53b-1483.pdf
	Identifier	ZNB-1998-53b-1483
	Volume	53

55	Author	Hans-Ulrich Meisch, JohannesA. Schmitt, Wolfgang Reinle	Requires cookie*
	Title	Schwermetalle in höheren Pilzen Cadmium, Zink und Kupfer Heavy Metals in Higher Fungi Cadmium, Zinc, and Copper
	Abstract	In a series of 190 samples, higher fungi, especially from the genus Agaricus, were analyzed by atomic absorption spectroscopy on their content of the trace metals cadmium, zinc, and copper. Cd was found to be present in high concentrations in some Agaricus species belonging to special taxonomic groups. In relation to soil concentrations, Cd is highly enriched in some Agaricus spec., the enrichment being a taxonomic criterion of special value. Among the remaining genera of higher fungi, only Leucoagaricus and Amanita showed similiar enrichment properties for cadmium. The chemically related metals Zn and Cu were found to be relative uniformely distributed in all analyzed fungi. No synergistic or antagonistic relationship between Cd and the other two metals could be detected in the mushrooms.
	Reference	(Z. Naturforsch. 32c, 172 [1977]; eingegangen am 28. Januar 1977)
	Published	1977
	Keywords	Cadmium, Zinc, Copper, Higher Fungi, Agaricus
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	TEI-XML for	default:Reihe_C/32/ZNC-1977-32c-0172.pdf
	Identifier	ZNC-1977-32c-0172
	Volume	32

56	Author	Heinz Rupp, K., Jozef Verplaetse, Rene Lontie	Requires cookie*
	Title	Binuclear Copper Electron Paramagnetic Resonance Signals of a-Methemocyanin of Helix pomatia
	Abstract	The binuclear electron paramagnetic resonance signals o f a-methemocyanin o f Helix pomatia were investigated at liquid helium temperatures. These signals were completely eliminated by the addition of fluoride and enhanced in the presence o f chloride, which did not alter the saturation behavior. The triplet nature of the signal at g = 4.59 was confirmed by the low power-saturation. The addition of nitrite at pH 5.0 and 0° C yielded slowly and reversibly a seven-line half-field signal. On lowering the temperature the intensity of the triplet signals increased to the lowest tem perature reached 4.2 K, excluding a strong exchange coupling.
	Reference	Z. Naturforsch. 35c, 188—192 (1980); received September 18/November 17 1979
	Published	1980
	Keywords	Copper, Electron Paramagnetic Resonance, Hemocyanin, Microwave Power Saturation
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	TEI-XML for	default:Reihe_C/35/ZNC-1980-35c-0188.pdf
	Identifier	ZNC-1980-35c-0188
	Volume	35

57	Author	R. Om, G., EligiuszS. Erafin, JanuszM. Azur	Requires cookie*
	Title	The Kinetics of the Reaction of Thiocyanate and Nitrite Ions with Orconectes limosus Oxyhemocyanin
	Abstract	The time course of the reaction of oxyhemocyanin from the arthropod Orconectes limosus with SCN" and N 0 2 " was investigated. After addition of one of these anions to oxyhemocyanin solu tion an exponential decay of A 340 was found, indicating a removal of oxygen from the active site. The order of reaction with respect to ligand was about 3 for thiocyanate and about 1 for nitrite. On this basis, a possible arrangement of ligands in the active site has been proposed. The final product of reaction with SCN" yielded a mononuclear copper EPR spectrum while the reaction product with N 07 gave a characteristic spectrum of two coupled Cu2+ ions. It was possible to remove the ligands from the active site by dialysis. The reaction patterns showed distinct changes in a narrow pH range, 5.3—6.5. A possible effect of structural alterations of the protein moiety on the course of the reaction of oxyhemocyanin with ligands is suggested.
	Reference	Z. Naturforsch. 40c, 677—681 (1985); received February 4 1985
	Published	1985
	Keywords	Hemocyanin, Reaction Kinetics, Copper, Electron Paramagnetic Resonance
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	TEI-XML for	default:Reihe_C/40/ZNC-1985-40c-0677.pdf
	Identifier	ZNC-1985-40c-0677
	Volume	40

58	Author	M. Ciscato3 ', J. Vangronsveldb, R. Valcke3	Requires cookie*
	Title	Effects of Heavy Metals on the Fast Chlorophyll Fluorescence Induction Kinetics of Photosystem II: a Comparative Study
	Abstract	The effects of toxic concentrations of Cu, Zn and Cd on the fast induction kinetics of fluorescence from photosystem(PS)II were investigated in a comparative way. The fast fluo rescence transient from primary leaves of m etal-treated bean plants was studied. During several days after metal application, the time course of the changes induced by the different metals was monitored. The results evidenced not only a different time course of the changes in fluorescence related parameters for the three metals, but also different effects on the fluorescence induction kinetics, which could possibly be linked to different mechanisms of action of the metals.
	Reference	Z. Naturforsch. 54c, 735 (1999); received November 8 1998/M arch 10 1999
	Published	1999
	Keywords	Cadmium, Chlorophyll Fluorescence, Copper, Heavy Metals, Zinc
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	TEI-XML for	default:Reihe_C/54/ZNC-1999-54c-0735.pdf
	Identifier	ZNC-1999-54c-0735
	Volume	54

59	Author		Requires cookie*
	Title	Über Oxocuprate, XXI
	Abstract	Bariumoxohalogenocuprate(II) mit Strukturbeziehungen zu BaCu02 About Oxocuprate s, X X I Barium Oxohalocuprates(II) with Structure Relationships to B aC u02 R. K ip k a und H k. M ü l l e r -B u s c h b a u m In stitu t für A norganische Chemie der C hristian-A lbrechts-U niversität K iel A ttem p ts to prepare BaCuO-2 single crystals w ith a flux of BaCl2 and BaBi'2 respectively lead to new oxo h a lo cu p ra tes(II): B a44Cu4s0 8 7 Cl4 (A) and B assC ussO nsB ^ (B). Single crystals were in v estig a ted b y X -ra y m ethods (cubic unit cell: (A) a = 1827 pm , (B) a = 1830.3 pm , space group 0 ® -lm 3 m). The com plicated crystal structures o f both com pounds are discussed. There are very in terestin g relationships to BaCu0 2 .
	Reference	(Z. Naturforsch. 32b, 124—126 [1977]; eingegangen am 23. November 1976)
	Published	1977
	Keywords	B arium, Copper, O xygen, X -ray, Crystal Structure
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	TEI-XML for	default:Reihe_B/32/ZNB-1977-32b-0124.pdf
	Identifier	ZNB-1977-32b-0124
	Volume	32

60	Author	Peter Klüfers, Hermann Neumann, Albrecht Mewis, Hans-Uwe Schuster	Requires cookie*
	Title	CaAl2Si2-Typ, VIII [1] AB2X2 Compounds with the CaAl2Si2 Structure, VIII [1]
	Abstract	Thirteen new compounds were synthesized. They are supposed to crystallize with_ the CaAl2Si2 type of structure (space group P3ml) with the following constants:
	Reference	Z. Naturforsch. 35b, 1317—1318 (1980); eingegangen am 12. Mai 1980
	Published	1980
	Keywords	2a-and 2b-Elements, Yttrium, Copper, Rare Earth Elements, Pnictides
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	TEI-XML for	default:Reihe_B/35/ZNB-1980-35b-1317_n.pdf
	Identifier	ZNB-1980-35b-1317_n
	Volume	35

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