| 2 | Author
| DennisG. Brown, WilliamJ. Hughes | Requires cookie* | | Title
| Copper(II) Complexes Containing 3-n-Nonylcatechol: Preparation and Ligand Oxidation  | | | Abstract
| Ternary copper(II) complexes containing the dianion of 3-n-nonylcatechol and a number of bidentate nitrogen containing counter ligands have been prepared and charac-terized. It has been demonstrated that, in the presence of oxygen, the catecholato ligand undergoes intradiol ring cleavage in a fashion similar to that carried out by intradiol aromatic dioxygenases. The 3-n-nonylcatecholato ligand was chosen as an analog for the naturally occuring 3-pentadecylcatechols or "urushiols" which are the active allergens in plants such as poison ivy. | | |
Reference
| Z. Naturforsch. 34b, 1408—1412 (1979); received June 19 1979 | | |
Published
| 1979 | | |
Keywords
| Copper, Dioxygenase, Urushiol Model, Catechol | | |
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| default:Reihe_B/34/ZNB-1979-34b-1408.pdf | | | Identifier
| ZNB-1979-34b-1408 | | | Volume
| 34 | |
3 | Author
| Wolfgang Döring, Werner Seelentag, Werner Buchholz, Hans-Uwe Schuster | Requires cookie* | | Title
| Ternäre Alkalimetallverbindungen vom Mg32(Zn,Al)49-Typ mit Elementen der 4. Hauptgruppe Ternary Compounds of the Mg32(Zn, Al)49-Type Structure with Alkali Metals and IV B-Elements  | | | Abstract
| In the ternary systems Li-Cu-Si, Li-Ni-Si and Na-Au-Si (Ge, Sn) five phases could be prepared and characterized by single crystal investigations, which crystallize in a cubic body-centered lattice and are related to the Mg32(Zn, Al)49-type structure (T-phases). | | |
Reference
| Z. Naturforsch. 34b, 1715—1718 (1979); eingegangen am 26. Juli 1979 | | |
Published
| 1979 | | |
Keywords
| Ternary Phases, Lithium, Sodium, Copper, Gold | | |
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| | | | TEI-XML for
| default:Reihe_B/34/ZNB-1979-34b-1715.pdf | | | Identifier
| ZNB-1979-34b-1715 | | | Volume
| 34 | |
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