| | 1 | Author
| Christian Egger, Ulrich Schubert | Requires cookie* | | | Title
| Metallkomplexe in Anorganischen Matrices, 5 [1] Katalytische Silanoxidation an einem heterogenisierten Rhodium-Komplex M etal Complexes in Inorganic Matrices, 5 [1] Catalytic Silane Oxidation at a Heterogenized Rhodium Complex  | | | | Abstract
| A heterogenized rhodium complex, prepared by sol-gel processing of Rh(CO)Cl[PPh2C H 2C H 2Si(OEt)3]2 and Si(OEt)4, is shown to catalyze the conversion of the si lanes H4_"SiPh" (n = 1 -3) or (H M e2Si)20 to (poly)siloxanes by air or water. Using T H F as a solvent, the silanoles Ph3SiOH or Ph2Si(OH)2 are obtained instead. The reaction of phenyl-acetic acid or acetic acid with HSiPh3 to give silyl esters is catalyzed by the same com pound. | | | |
Reference
| Z. Naturforsch. 46b, 783—788 (1991); eingegangen am 14. Januar 1991 | | | |
Published
| 1991 | | | |
Keywords
| Heterogenized Rhodium Complex, Catalysis, Silanes, Silanoles, Siloxanes, Silyl Esters | | | |
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| default:Reihe_B/46/ZNB-1991-46b-0783.pdf | | | | Identifier
| ZNB-1991-46b-0783 | | | | Volume
| 46 | |
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