1 | Author | Walter Strohmeier, Johannes-Peter Stasch | Requires cookie* |
Title | Photoaktivierung und Photosensibilisierung des homogenen Hy drierungs -Katalysators IrCl(CO) [P(i-C3H7)3] 2 Photoactivation and Photosensitization of the Homogeneous Hydrogenation Catalyst IrCl(CO)[P(i-C3H7)3]2 ![]() | ||
Abstract | Under irradiation with monochromatic light of X < 407 nm homogeneous hydrogenation of acrylic ethvlester with the catalyst IrCl(CO)[P"(i-C3H7)3]2 is much faster than in the dark reaction. Not the catalyst but the hydrido-complex is photochemically activated. With the sensitizer pentacene, photoactivation occurrs with visible light of X < 578 nm already. | ||
Reference | Z. Naturforsch. 34b, 755—758 (1979); eingegangen am 31. Januar 1979 | ||
Published | 1979 | ||
Keywords | Photoactivation, Photosensitization, Hydrogenation, Catalysis | ||
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