| 1 | Author | Heide Lindenberger, Reiner Birk, Olli Orama, Gottfried Huttner, Heinz Berke | Requires cookie* |
| Title | Ketenylidentriphenylphosphoran-Komplexe Ketenylidenetriphenylphosphorane Complexes  | ||
| Abstract | Ketenylidenetriphenylphosphorane complexes of the type L"MC(CO)PPh3 L"M = CpMn(CO)2 (2a), CpRe(CO)2 (2b) and Fe(CO)4 (3) are obtained by CO substitution reactions. The synthesis of 3 at 80 °C is accompanied by the formation of a Fe2(CO)6 compound with a bridging a-metallated formyl(triphenylphosphane)carbido ligand. From ethylation of 3 arises an Fe2(CO)6 ferrol-type complex 5. | ||
| Reference | Z. Naturforsch. 43b, 749—757 (1988); eingegangen am 5. Oktober/22. Dezember 1987 | ||
| Published | 1988 | ||
| Keywords | Heterocumulene Ylide Complexes, a-Metallation, Ferroles, X-Ray | ||
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