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'a Hydroxymethylperoxyl Radical' in keywords
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1978 (1)
1Author    Eberhard Bothe, Dietrich Schulte-FrohlindeRequires cookie*
 Title    Aqueous Solution  
 Abstract    The bimolecular decay of the hydroxymethylperoxyl radical in aqueous solution (k = 2.1 x 10 9 M _1 s _1) leads mainly (80%) to one molecule of hydrogen peroxid and to two molecules of formic acid. 2 HOCHsOO--> H202 + 2 HCOOH Deuterium kinetic isotope effects show that the decay occurs at room temperature via a short lived (t < 10 -4 s) tetroxid. 
  Reference    Z. Naturforsch. 33b, 786—788 (1978); received February 20 1978 
  Published    1978 
  Keywords    a-Hydroxymethylperoxyl Radical, Pulse Radiolysis, Conductivity, Oxydation of Methanol 
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 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-0786.pdf 
 Identifier    ZNB-1978-33b-0786 
 Volume    33