| 1 | Author | Eberhard Bothe, Dietrich Schulte-Frohlinde | Requires cookie* |
| Title | Aqueous Solution  | ||
| Abstract | The bimolecular decay of the hydroxymethylperoxyl radical in aqueous solution (k = 2.1 x 10 9 M _1 s _1) leads mainly (80%) to one molecule of hydrogen peroxid and to two molecules of formic acid. 2 HOCHsOO--> H202 + 2 HCOOH Deuterium kinetic isotope effects show that the decay occurs at room temperature via a short lived (t < 10 -4 s) tetroxid. | ||
| Reference | Z. Naturforsch. 33b, 786—788 (1978); received February 20 1978 | ||
| Published | 1978 | ||
| Keywords | a-Hydroxymethylperoxyl Radical, Pulse Radiolysis, Conductivity, Oxydation of Methanol | ||
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