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'a Hydroxyalkylperoxyl Radicals' in keywords Facet   section ZfN Section B:Volume 033  [X]
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1978 (1)
1Author    Nien Man, Clemens Schuchmann, Von SonntagRequires cookie*
 Title    Free Radical Induced Oxidation of Neutral Aqueous Solutions of D-Glucose in the Presence of Oxygen -a Non-Chain Process  
 Abstract    Oxygenated 1 M aqueous solutions of 2-methyltetrahydrofuran (MTHF) or D-glucose were y-irradiated, and G(total peroxide) was determined as a function of dose rate and temperature. Whereas MTHF was oxidized by a chain process, D-glucose was not. The peroxyl radicals derived from D-glucose rapidly eliminate H02". At natural pH H02' (pK = 4.75) is largely deprotonated. O2— does not propagate a chain. 
  Reference    Z. Naturforsch. 33b, 329—331 (1978); received November 25 1977 
  Published    1978 
  Keywords    Autoxidation, D-Glucose, 2-Methyltetrahydrofuran, a-Hydroxyalkylperoxyl Radicals, y-Irradiation 
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 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-0329.pdf 
 Identifier    ZNB-1978-33b-0329 
 Volume    33