| | 1 | Author
| Anne Utzolino, Karsten Bluhm | Requires cookie* | | | Title
| Cox 5Ti0 5(B 0 3) 0 and Co! 5Zro.5(B 0 3) 0  | | | | Abstract
| Single crystals of Co15Tio.5(B 0 3)0 (I) and Coj 5Zr0 5(BO3)O (I I) were obtained by a B20 3 flux technique. Both compounds crystallize with orthorhombic symmetry, space group D -Pnma (Nr. 62), I a = 928.1; b = 311.1; c = 940.1 pm; Z = 4 and I I a = 949.5; b = 323.42; c = 934.7 pm; Z = 4. The compounds are isotypic to the mineral warwickite. All metal ions are octahedrally coordinated by oxygen ions. The structure contains isolated, trigonal planar B 0 3 units and oxygen that is not coordinated to boron. Die Synthese und Kristallstruktur von cobalthaltigen Boratoxiden: Coi^Tio,5(B03)0 und C o i?5Zr<),5(B03)0 | | | |
Reference
| Z. Naturforsch. 50b, 1653—1657 (1995); eingegangen am 4. Mai 1995 | | | |
Published
| 1995 | | | |
Keywords
| Cobalt, Titanium, Zirconium, Borate Oxide, Crystal Structure, X-Ray | | | |
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| default:Reihe_B/50/ZNB-1995-50b-1653.pdf | | | | Identifier
| ZNB-1995-50b-1653 | | | | Volume
| 50 | |
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