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1997 (1)
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 Title    Mehrkernige CpZr(IV)-und CpHf(IV)-Komplexe mit Oximatobrücken  
 Abstract    o ly n u cle ar C p Z r(IV) a n d C p H f(IV) C o m p le x e s w ith O x im a to B rid g e s W olfgang B ra u n w a rth , U lf T hew alt* The mono-cyclopentadienyl metal complexes C pZrC l3(dme) and CpHfCl3(dme) react with acetone oxime in the presence of triethylamine to form the isotypic dinuclear complexes [CpMCl2]2(M-ONCMe2)2(//-HONCM e2) (1: M = Zr; 2: M = Hf). 1 and 2 contain two oximato bridges and one oxime bridge. In the presence of w ater the reaction gives, with partial hydro­ lysis, the cyclic trinuclear compounds [CpZrCl]3(a3-0)(M3-0 H)(« -0 N C M e 2)3«/:Me2C N 0 H 
  Reference    Z. Naturforsch. 52b, 1011—1018 (1997); eingegangen am 4. März 1997 
  Published    1997 
  Keywords    Zirconium Complexes, Hafnium Complexes, Oximato Ligands, Oxime Ligand, Molecular Structure 
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 TEI-XML for    default:Reihe_B/52/ZNB-1997-52b-1011.pdf 
 Identifier    ZNB-1997-52b-1011 
 Volume    52