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'Zinc and Tungsten Complexes' in keywords
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1983 (1)
1Author    HerbertW. Roesky, Habib Djarrah, Manfred Thomas, Berat Krebs, Gerald HenkelRequires cookie*
 Title    Oxidationsreaktionen von Phosphanen mit Schwefeldioxid Oxidation Reactions of Phosphanes with Sulfur Dioxide  
 Abstract    Sulfur dioxide can be used as an oxidizer in the reaction of Zn(S02)re(AsFe)2 and tetra-phenyldiphosphane. The resulting product is the tetraphenyldiphosphane dioxide complex of composition Zn[02P2(C6H5)4]3(AsF6)2 (1)-The same compound is formed by the direct reaction of the zinc salt with 02P2(C6Hs)4-When Zn(S02)«(AsF6)2 is treated with P[0 = P(0C2H5)2]3 in liquid S02, Zn{P[0 = P(0C2H5)2]3}2(AsF6)2 (2) is formed. The struc-ture of 2 was investigated by means of an X-ray single crystal analysis. 2 crystallizes in space group P~31c with a = b= 11.967(3) and c = 21.202(4) Ä. 
  Reference    Z. Naturforsch. 38b, 168—171 (1983); eingegangen am 25. Oktober 1982 
  Published    1983 
  Keywords    Zinc and Tungsten Complexes, X-ray Structure, 31 P NMR Spectra 
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 TEI-XML for    default:Reihe_B/38/ZNB-1983-38b-0168.pdf 
 Identifier    ZNB-1983-38b-0168 
 Volume    38