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'Zinc Cyanide C om plex' in keywords Facet   section ZfN Section B  [X]
Facet   Publication Year 1999  [X]
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1Author    Joachim Pickardt, Pirka WischlinskiRequires cookie*
 Title    Kristallstruktur des "supramolekularen" Komplexes [K(Benzo-18-krone-6)][Zn(CN)3]*H20 mit einem polymeren kettenförmigen Tricyanozincat-Anion Crystal Structure of the "Supramolecular" Complex [K(benzo-18-crown-6)][Zn(CN)3] *H20 with a Polymeric Tricyano Zincate Anion with Chain Structure  
 Abstract    Crystals o f the com plex [K (benzo-18-crown-6][Zn(CN)3] H20 were obtained from a solution o f Z n(C N)2, KCN, and b en zo-18-crown-6 in water/methanol. The compound crystallizes in the triclinic space group PI (no. 2),: Z = 2, a = 818,6(5), b = 1236,7(8), c = 1359,6(6) pm, a = 67,02(4), ß = 87,38(4), 7 = 75,46(5). Each Zn atom is bonded to one bridging cyanide ion to give chains -Z n (C N)Z n -, and to two terminal CN groups. The N atom o f one o f the terminal CN groups interacts with a potassium ion o f the [K (benzo-18-crow n-6)]+ unit. The coordination spheres o f the K ions are completed by water molecules, which in turn form hydrogen bonds to N atoms o f terminal CN groups o f neighbouring chains, whereby puckered sheets are formed. 
  Reference    Z. Naturforsch. 54b, 747 (1999); eingegangen am 10. Februar 1999 
  Published    1999 
  Keywords    Zinc Cyanide C om plex, Crown Ether Complex, Crystal Structure 
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 TEI-XML for    default:Reihe_B/54/ZNB-1999-54b-0747.pdf 
 Identifier    ZNB-1999-54b-0747 
 Volume    54