| | 1 | Author
| Oppermann, S. Herrera, DaoQuoc Huong | Requires cookie* | | | Title
| Untersuchungen zum chemischen Transport von YX3 mit A1X3 und zur Existenz von gasförmigen und festen Komplexen YA13 X12 (X = Br, I) Investigations on the Chemical Transport Reaction of YX3 with A1X3 and on the Existence of Gaseous and Solid Complexes YA13 X 12 (X = Br, I) H  | | | | Abstract
| The dominant gaseous complexes YAl3B r12 and YA13I 12 were generated in the chemical trans port reactions of YBr3 with AlBr3 and YI3 with A1I3. The enthalpy of formation Z\H£(YAl3B r12,gi298) = -484,5 ± 6 kcal/mol and the standard entropy S°(YA13B 12 g 298) = 290,0 ± 7,5 cal/K mol have been calculated. It follows from total pressure measurements of mixtures of YBr3 s with AlBr3 1 and YI3 s with A1I3 b respectively, that complexes YAl3B r12 s and YA13I 12 s do not exist up to the boiling points of the aluminium trihalides. | | | |
Reference
| Z. Naturforsch. 53b, 361—366 (1998); eingegangen am 1. Dezember 1997 | | | |
Published
| 1998 | | | |
Keywords
| Chemical Transport Reaction, Yttrium Aluminium Halides, Enthalpy of Formation, Standard Entropy, Total Pressure Measurements | | | |
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| default:Reihe_B/53/ZNB-1998-53b-0361.pdf | | | | Identifier
| ZNB-1998-53b-0361 | | | | Volume
| 53 | |
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