| 1 | Author | Hidenari Inoue, Ekkehard Fluck | Requires cookie* |
| Title | Mößbauer-und Röntgenphotoelektronen-spektroskopische Untersuchungen an Berlinerblau-Analoga des Typs Fe[M B (CN)6] Mößbauer and X-Ray Photoelectron Spectroscopic Studies on Prussian Blue Analogs of the Type Fe[M B (CN)6]  | ||
| Abstract | Prussian Blue analogs of the type Fe[M B (CN)e] (M B = Pd and Pt) crystallize in the face-centered cubic system: space group Fm3m-0^, Z = 4. Magnetochemical and Mößbauer spectroscopic measurements have revealed that nitrogen-coordinated iron(II) ions and carbon-coordinated M B (IV) ions are in the high spin state and in the low spin state, respectively, in the temperature range 4.2 to 300 K. Upon the formation of Fe[M B (CN)ß] from K2[M B (CN)6], the binding energies of N Is, Pd 3d5/2 and Pt 4f7/2 increase while the C 1 s binding energy decreases. This tendency could be interpreted in terms of the inductive effect of iron(II) ions attached to the nitrogen end of cyanide ligands. | ||
| Reference | Z. Naturforsch. 38b, 687—691 (1983); eingegangen am 7. Februar 1983 | ||
| Published | 1983 | ||
| Keywords | Mößbauer Spectra, X-Ray Photoelectron Spectra, Prussian Blue Analogs | ||
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