| | 1 | Author
| Dieter Sellmann, Susanne Emig, FrankW. Heinemann, Falk Knoch | Requires cookie* | | | Title
| Ubergangsmetallkomplexe mit Schwefelliganden, CXXXIII [1]. Synthese, Struktur und Eigenschaften neuer Fe11-Komplexe mit [FeN2S2]-Gerüsten Transition M etal Complexes with Sulfur Ligands, C X X X III [1]. Synthesis, Structure, and Properties o f N ew F e1 1 Complexes with [ F e N ^ ] Cores  | | | | Abstract
| In order to obtain suitable precursors for iron complexes that model the reactivity o f the active sites o f nitrogenases, the coordination chemistry of the [Fe('N2H2S2')] fragment was systematically investigated('N2 H2S2'2~ = l,2-ethanediamine-N,N'-bis(2-benzenethiolate)(2-)). One-pot reactions o f FeCl2 -4H20 with the tetradentate amine-thiolate ligand 'N2 H2S2'2_ and CO, PR,, or P(O R) 3 yielded the complexes [Fe(CO)2('N 2 H2S2')] (1), [Fe(CO)(PR3)('N 2H2S2')] | | | |
Reference
| Z. Naturforsch. 53b, 1461—1474 (1998); eingegangen am 9. Juli 1998 | | | |
Published
| 1998 | | | |
Keywords
| Iron Sulfur Complexes, Amine Ligands, Phosphane Ligands, X-Ray Data Cyclic Voltammetry | | | |
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| default:Reihe_B/53/ZNB-1998-53b-1461.pdf | | | | Identifier
| ZNB-1998-53b-1461 | | | | Volume
| 53 | |
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