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Facet   Publication Year 1995  [X]
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1Author    Haruhiko Yokoyama, Saeko Suzuki, Masuo Goto, Kazuteru Shinozaki, Yuriko Abe, Shin-Ichi IshiguroRequires cookie*
 Title    X -R a  
 Abstract    y D if fr a c tio n S tu d y o f th e S o lv a tio n S tr u c tu r e o f th e C o b a lt (I I) I o n in N ,N -D im e th y lf o rm a m id e S o lu tio n Dedicated to Prof. Hitoshi Ohtaki on the occasion of his 60th birthday The solvation structure of Co2+ in N,N-dimethylformamide (DMF) has been studied by X-ray diffraction measurements on cobalt (II) and magnesium (II) Perchlorate solutions of the same concen­ tration, using an isostructural substitution method. The radial distribution function revealed three distinct peaks assigned to the oxygen, amido carbon (CJ, and nitrogen atoms of six planar DMF molecules in the first coordination sphere around the metal atom. The distance from the cobalt atom to each atom (O, Cx, N) is 213,299, and 423 pm, respectively. This indicates that the Co-O-Cj bond angle is 122-123° and the metal atom is close to the O-Cj-N plane of the DMF molecule. 
  Reference    Z. Naturforsch. 50a, 301—306 (1995); received September 28 1995 
  Published    1995 
  Keywords    Cobalt, N,N-dimethylformamide, Solvation, X-ray, Structure 
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 TEI-XML for    default:Reihe_A/50/ZNA-1995-50a-0301.pdf 
 Identifier    ZNA-1995-50a-0301 
 Volume    50