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2001 (1)
1Author    E. Mikuli, A. Migdał-Mikuli, I. Natkanieca, B. GradRequires cookie*
 Title    Phase Transitions and Water Dynamics of [Co(H20 ) 6](C104)2 and [Mn(H20 ) 6](BF4)2 Studied by Neutron Scattering Methods  
 Abstract    Inelastic incoherent neutron scattering (IINS) spectra and neutron powder diffraction (NPD) patterns, registered for [Co(H20) 6](C104)2 at 18 -270 K and for [Mn(H20) 6](BF4)2 at 18 -230 K, provided evidence that these crystals possess three solid phases in these ranges of temperatures. In both compounds the phase transition occurring at T C3 is connected with a change of the crystal structure, and that occurring at T C2 with a change in the rate of the reorientational motions of H20 ligands. 
  Reference    Z. Naturforsch. 56a, 244 (2001); received December 12 2000 
  Published    2001 
  Keywords    Hexaaquacobalt(II) chlorate(VII) and Hexaaquamanganese(II) tetrafluoroborate, Phase Transitions, Structural Changes, Water Reorientation, Neutron Scattering 
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 TEI-XML for    default:Reihe_A/56/ZNA-2001-56a-0244.pdf 
 Identifier    ZNA-2001-56a-0244 
 Volume    56