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'Vibrational Spectra' in keywords Facet   Publication Year 1993  [X]
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1Author    Chrystel Hagen, Hanns-D Ieter AmbergerRequires cookie*
 Title    Zur Elektronenstruktur hochsymmetrischer Verbindungen der /-Elemente, XXV.III) Single Crystals for Chemical Syntheses and Physical Investigations  
 Abstract    Züchtung hochreiner Tris[bis(trimethylsilyl)amido]lanthanoid(III)-Einkristalle für chemische Synthesen und physikalische Untersuchungen The Electronic Structure o f Highly Symmetrical Compounds o f the /-Elem ents, XXV. Grow th of U ltrapure Tris[bis(trimethylsilyl)amido]lanthanide(Tris[bis(trimethylsilyl)amido]lanthanide(III 
  Reference    Z. Naturforsch. 48b, 1365—1371 (1993); eingegangen am 17. Juni 1993 
  Published    1993 
  Keywords    ) Complexes, Large Oriented Single Crystals, Optical Spectra, Vibrational Spectra 
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 TEI-XML for    default:Reihe_B/48/ZNB-1993-48b-1365.pdf 
 Identifier    ZNB-1993-48b-1365 
 Volume    48 
2Author    ". B. Preparation, 13cN., M. R., Vibrational Spectra, W. Preetz, A. Franken, M. R. AthRequires cookie*
 Title    Darstellung, UB-, 13C-NM R-und Schwingungsspektren der c/öso-Hexaborate [B6H 5(C N )|2~ und m -[B 6H4(CN)2l2_ sowie Kristallstruktur von Cs2[B6H 5(CN)|  
 Abstract    of the c/oso-Hexaborates [B6H 5(CN)]2~ and c/s-[B6H 4(C N)2]2-, and the Crystal Structure o f Cs2[B6H 5(CN)] By reaction o f Cs2[B6H 6] with in situ generated dicyanogen in aqueous alkaline solution the m onocyanohydrohexaborate C s2[B6H5(CN)] and the dicyanohydrohexaborate cis-Cs,[B6H4(C N)2] are formed. The com pounds have been separated by ion exchange chrom atog­ raphy on diethylaminoethyl cellulose. The crystal structure o f Cs2[B6H5(CN)] was determined from single crystal X-ray diffraction analysis; monoclinic, space group P 2 Ja with a = 9.540(8), b = 9.977(3), c = 10.578(2) Ä, ß = 105.06(2)°. The B6 octahedron is compressed in the direction o f the nearly linear B -C N bond by about 5%, with bond lengths between 1.71 and 1.76Ä . The "B N M R spectra o f the two com pounds reveal the features o f substituted B6 cages with C4v and C2v point symmetry. In the l3C N M R spectrum o f Cs2[B6H 5(CN)] a quartet at -139 ppm with '/(C ,B) 92 Hz is observed. The IR and Raman spectra exhibit very strong CN stretching bands for Cs2[B6H5(CN)] at 2149, and for m -C s2[B6H4(C N)2] at 2170 c tr r 1. 
  Reference    Z. Naturforsch. 48b, 598—6 (1993); eingegangen am 7. Dezember 1992 
  Published    1993 
  Keywords    M onocyanohydrohexaborate, m -Dicyanohydrohexaborate, Crystal Structure, 11B N M R Spectra, Vibrational Spectra 
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 TEI-XML for    default:Reihe_B/48/ZNB-1993-48b-0598.pdf 
 Identifier    ZNB-1993-48b-0598 
 Volume    48 
3Author    Rolf Minkwitz, Birgit BäckRequires cookie*
 Title    Über die Darstellung und spektroskopische Charakterisierung von CH3S(Br)F+SbF6" [ 1] On the Preparation and Spectroscopic Characterization of C H 3S(B r)F+SbF6~ [1]  
 Abstract    C H ,S(H)+SbF6" reacts in H F as solvent with Br2 to form C H 3S(Br)F+SbF6". The salt is stable below 195 K and has been characterized by vibra­ tional and 1H and l9F N M R spectroscopy. 
  Reference    Z. Naturforsch. 48b, 694—6 (1993); eingegangen am 30. Dezember 1992 
  Published    1993 
  Keywords    Bromofluorosulfonium Salt, Vibrational Spectra, 'H N M R Spectra, l9F N M R Spectra 
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 TEI-XML for    default:Reihe_B/48/ZNB-1993-48b-0694_n.pdf 
 Identifier    ZNB-1993-48b-0694_n 
 Volume    48