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'Vibration Spectrum' in keywords Facet   Publication Year 1987  [X]
Facet   section ZfN Section A:Volume 042  [X]
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1Author    Robert Becker, Wolfgang Brockner, Brigitte EisenmannRequires cookie*
 Title    Kristallstruktur und Schwingungsspektrum des Thallium(I)-Zinn(II)-ortho-Thiophosphates TlSnPS4  
 Abstract    TlSnPS4 crystallizes in the orthorhombic system, space group P na21 (Nr. 33), Z = 4 with the lattice constants a = 1175.8 (5) pm, b = 890.1 (4) pm, c = 663.3 (4) pm. In the structure are sligthly distorted discrete PS4_ anions. The far infrared, infrared and Raman spectrum is assigned on the basis o f P S]-units with C 3v symmetry. According to the DTA data the m elting point for TlSnPS4 is 575 ± 5 °C. The title compound is not moisture sensitive and semi-conducting. 
  Reference    Z. Naturforsch. 42a, 1309—1312 (1987); received Septem ber 15 1987 
  Published    1987 
  Keywords    ortho-Thiophosphate, TlSnPS4, Crystal Structure, Vibration Spectrum 
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 TEI-XML for    default:Reihe_A/42/ZNA-1987-42a-1309.pdf 
 Identifier    ZNA-1987-42a-1309 
 Volume    42