| | 1 | Author
| S. J. Cyvin, B. N. Cyvin, C. Wibbelmann, R. Becker, W. Brockner, M. Parensen | Requires cookie* | | | Title
| Synthesis, Vibrational Spectra and Normal Coordinate Analysis of Cesium-Hexathiohypodiphosphate CS4P2S6  | | | | Abstract
| The title compound has been prepared by elemental synthesis at high temperatures and also by reaction of Na 4 P 2 S 6 • 6 H 2 0 with CsCl in aqueous solution. Both reaction products have closely related vibrational spectra which are assigned on the basis of a P 2 Sg anion with perturbed D 3d symmetry. A normal coordinate analysis has been performed using a force Field with 4 initial force constants. The refined force Field, potential energy distribution (PED), mean amplitudes of vibration and Coriolis coupling constants are given. | | | |
Reference
| Z. Naturforsch. 40a, 709—713 (1985); received May 3 1985 | | | |
Published
| 1985 | | | |
Keywords
| Cesiumhexathiohypodiphosphate, Cs 4 P 2 S 6, Vibration Spectra, Normal Coordinate Analysis | | | |
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| default:Reihe_A/40/ZNA-1985-40a-0709.pdf | | | | Identifier
| ZNA-1985-40a-0709 | | | | Volume
| 40 | |
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