Go toArchive
Browse byFacets
Bookbag ( 0 )
'Vanadato Periodate' in keywords Facet   section ZfN Section B  [X]
Results  1 Item
Sorted by   
Publication Year
1982 (1)
1Author    Rainer Mattes, Kurt-Ludwig RichterRequires cookie*
 Title    Darstellung und Struktur des Polyvanadato-periodates Na6 [H2V2I2016] * 10 H20 Preparation and Crystal Structure of the Heteropoly Periodate Na6[H2V2I20i6] * 10 H2O  
 Abstract    The structure of the heteropoly periodate ion [H2V2I20i6] 6 ~ has been determined in its Na salt at —150 °C by single crystal X-ray diffraction with 1909 reflections and refined to F = 0.022 (R'= 0.028). Na6[H2V2I2Oi6] • 10 HaO crystallizes in the triclinic space group PI with a = 11.407(5), b = 8.865(3), c = 6.105(3)1, a = 82.07(3)°, /? = 84.24(4)° y = 70.23(3)°, V = 574.5 A 3 , Z = 1. The [H2V2I2Oi6] 6 ~ anion consists of edge and corner sharing 106 octahedra and VO5 square pyramids. The vibrational spectra clearly indicate the presence of VO(terminal)2 groups. 
  Reference    Z. Naturforsch. 37b, 1241—1244 (1982); eingegangen am 17. Mai 1982 
  Published    1982 
  Keywords    Heteropoly Periodate, Vanadato Periodate, Crystal Structure 
  Similar Items    Find
 DEBUG INFO      
 TEI-XML for    default:Reihe_B/37/ZNB-1982-37b-1241.pdf 
 Identifier    ZNB-1982-37b-1241 
 Volume    37