| 1 | Author
| DennisG. Brown, WilliamJ. Hughes | Requires cookie* | | Title
| Copper(II) Complexes Containing 3-n-Nonylcatechol: Preparation and Ligand Oxidation  | | | Abstract
| Ternary copper(II) complexes containing the dianion of 3-n-nonylcatechol and a number of bidentate nitrogen containing counter ligands have been prepared and charac-terized. It has been demonstrated that, in the presence of oxygen, the catecholato ligand undergoes intradiol ring cleavage in a fashion similar to that carried out by intradiol aromatic dioxygenases. The 3-n-nonylcatecholato ligand was chosen as an analog for the naturally occuring 3-pentadecylcatechols or "urushiols" which are the active allergens in plants such as poison ivy. | | |
Reference
| Z. Naturforsch. 34b, 1408—1412 (1979); received June 19 1979 | | |
Published
| 1979 | | |
Keywords
| Copper, Dioxygenase, Urushiol Model, Catechol | | |
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| default:Reihe_B/34/ZNB-1979-34b-1408.pdf | | | Identifier
| ZNB-1979-34b-1408 | | | Volume
| 34 | |
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