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1976 (1)
1Author    Rupert Herrmann, Helmut SchwarzRequires cookie*
 Title    On the Isomerisation and Fragmentation of Butenoic Acid Methyl Esters under Electron Impact  
 Abstract    Ion On the contrary to the photochemical behavior the title compounds do not isomerise to a common intermediate prior to or during electron impact induced fragmentation. The unusual methyl elimination from the trans (2)-butenoic acid methyl ester probably is ac-companied by a concerted [1.3] methoxy rearrangement from the ester function on to the ß carbon atom. 
  Reference    (Z. Naturforsch. 31b, 1013—1014 [1976]; eingegangen am 22. März 1976) 
  Published    1976 
  Keywords    Structure, Neighbouring Group Participation, Alkoxy Rearrangement, Mass Spectrometry, Unsaturated Esters 
  Similar Items    Find
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 TEI-XML for    default:Reihe_B/31/ZNB-1976-31b-1013_n.pdf 
 Identifier    ZNB-1976-31b-1013_n 
 Volume    31