| | 1 | Author
| Achim Müller, Stephan Dillinger3, Erich Krickemeyer3, Hartmut Bögge3, Winfried Plass3, Anja Stammler3, RobertC. Haushalterb | Requires cookie* | | | Title
| A Further Example for the Validity of the Concept of Unit Construction in Polyoxometalate Chemistry  | | | | Abstract
| The compound Na7[NaC{(M 0V20 4)3()U2-0 H)3H(PhP03)4}2] • 2 N2H4-26 H20 (formu lation with respect to the aggregate in the crystal) has been synthesized and character ized by single-crystal X-ray structure analysis (which alone does not allow the determi nation of the formula), UV/Vis/NIR/IR, 31 P{1H}, 'H and 23Na NMR spectroscopy as well as magnetic susceptibility measurements. The compound is formed under similar conditions as (NH2Me2)6[H2C(Mov204)604(/i2-C)H)i2(MoVIC)3)4]-Correspondingly, both cluster frame works are built up by the same {(Mov204)3(/i2-OH)3}3+ units. | | | |
Reference
| Z. Naturforsch. 52b, 1301—1306 (1997); received June 30 1997 | | | |
Published
| 1997 | | | |
Keywords
| Cluster, Polyoxomolybdates, Self-assembly, Unit Construction, Electronic Structure | | | |
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| default:Reihe_B/52/ZNB-1997-52b-1301.pdf | | | | Identifier
| ZNB-1997-52b-1301 | | | | Volume
| 52 | |
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