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1Author    M. Ohsen, Safarpour Haghighi, Heiner HomborgRequires cookie*
 Title    Darstellung und Eigenschaften von Bis(phthalocyaninato)lanthanaten und -ceraten Preparation and Properties o f Bis(phthalocyaninato)lanthanates and -cerates  
 Abstract    High yields of bisphthalocyaninates of lanthanum and cerium have been obtained in the strongly exothermic reaction of the dehydrated lanthanoid acetates with molten 1,2-di-cyanobenzene in the presence of potassium hydroxide or methylate. Salts of the type (cat)[M(Pc(2-))-,] (M = La, Ce) with different cations (cat+ = K. Bu4N, PNP. TDOA) have been isolated. The corresponding "Hydrogen salts" are obtained by thermal decomposition of (Bu4N)[M(Pc(2-))-,] at T > 350 C. The dimeric structure is confirmed by negative fast atom bombardement mass spectra. The redox properties have been investigated by cyclovoltam-metry and UV, VIS, MIR, FIR and resonance Raman (RR) spectra are reported. Electronic transitions between 2000 and 3000 cm 1 are observed in the low temperature RR spectra of (Bu4N)[Ce(Pc(2-))^] being RR enhanced at 470 nm. From the assignment to the higher transi­ tions within the symmetry split 5F5/2, :F7 manifolds of the f1 ground state of Ce3+ the crystal field parameters f4f = 610.5, B40 = 242.2 and B60 = 4.1 cm-1 have been determined. 
  Reference    Z. Naturforsch. 46b, 1641—1649 (1991); eingegangen am 18. Juni 1991 
  Published    1991 
  Keywords    Bis(phthalocyaninato)lanthanates Bis(phthalocyaninato)cerates, Vibrational Spectra, UV-VIS Spectra, Electronic Raman Spectra 
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 TEI-XML for    default:Reihe_B/46/ZNB-1991-46b-1641.pdf 
 Identifier    ZNB-1991-46b-1641 
 Volume    46