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'Tungsten' in keywords Facet   section ZfN Section B:Volume 033  [X]
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1978 (1)
1Author    Herbert Binder, Dieter SellmannRequires cookie*
 Title    Röntgen-photoelektronenspektroskopische Untersuchungen an Pentacarbonyl- Chrom-und -Wolfram-Komplexen mit Stickstoffliganden c X-ray Photoelectron Studies of Pentacarbonyl Chromium and Tungsten Complexes with Nitrogen Ligands  
 Abstract    The ionization energies of some chromium and tungsten pentacarbonyl complexes of the type [M(CO)5] xL (L = N2H2, N2H4, NH3; x = 1 or 2 for N2H4 or a; = 1 for N2H2) are reported. The results are discussed in terms of the effects of tr-donor and 7r-acceptor bonds on XPS data. Satellite lines, which can be explained in terms of a shake-up process, give information about the nature of the metal-ligand bond. These shake-up processes are, to a large extent, specific to the atoms of the acceptor groups. The spectroscopic and chemical importance of multi-peak structures of XPS bands is emphasised. 
  Reference    Z. Naturforsch. 33b, 173—179 (1978); eingegangen am 21. Dezember 1977 
  Published    1978 
  Keywords    X-ray, PE Spectra, Monosubstituted Pentacarbonyls, Chromium, Tungsten 
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 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-0173.pdf 
 Identifier    ZNB-1978-33b-0173 
 Volume    33