| 1 | Author | Saim Özkar, Zahide Özer | Requires cookie* |
| Title | 3C NMR Spectroscopic Study of Pentacarbonylacetonitrilemetal(O) Complexes of the Group 6 B Elements  | ||
| Abstract | The com plexes M (CO)5(C H 3C N) (M: Cr, M o, W) were obtained from the substitution o f TH F in M (C O)5(TH F) which has been generated by photolysis o f M(CO)6 in T H F and characterized by using IR , 'H N M R and l3C N M R spectrosco pies. The acetonitrile ligand is found to be N -bonded to the M (CO)5-moiety with a local C4v-symmetry. The effect o f the acetonitrile ligand on the metal-carbonyl bonding was discussed in terms o f l3C N M R chemical shifts. | ||
| Reference | Z. Naturforsch. 48b, 1431 (1993); received M ay 17 1993 | ||
| Published | 1993 | ||
| Keywords | Chromium, M olybdenum, Tungsten, Carbonyl, Acetonitrile | ||
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