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'Tritertiary Phosphines' in keywords Facet   Publication Year 1976  [X]
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1976[X]
1Author    Jochen Ellermann, HelmutA. LindnerRequires cookie*
 Title    Komplexchemie polyfunktioneller Liganden, XXXVIII  
 Abstract    Präparative und schwingungsspektroskopische Untersuchungen zum Reaktionsverhalten von Mn2(CO)10 gegenüber dem tritertiären Phosphin l.l.l-Tris(diphenylphosphinomethyl)äthan Complex Chemistry of Polyfunctional Ligands, XXXVIII 1 Preparative and Vibrational Spectroscopic Studies of the Reaction of Mn2(CO)10 with the Tritertiary Phosphine 1,1 ,l-Tris(diphenylphosphinomethyl)ethane Decacarbonyldimanganese reacts with the tritertiary phosphine l,l,l-tris(diphenylphos-phinomethyl)ethane (triphos) to give the ionic complex [Mn(CO)3triphos][Mn(CO)5]. Treatment of [Mn(CO)3triphos][Mn(CO)5] with Na[B(C6H5)4], HC104 and NH4PF6 yields the manganese (I) salts [Mn(CO)3triphos]Y (Y = B(C6H5)4, C104, PFe). The IR (2100-300 cm -1) and FIR spectra (350-200 cm -1) of all compounds are reported. Based on Ra-man polarization data the assignment of the v(CO) (Ai + E), <5(MnCO) (Ai + 2 E), j>(MnC) (Ai + E) and v(MnP) (Ai) modes was possible for the coordination polyhedra cts-Mn(CO)3P3 (point group C3v). The i'(MnP) (E) mode was unobserved due to its very low frequency. 
  Reference    (Z. Naturforsch. 31b, 1350—1355 [1976]; eingegangen am 23. Juli 1976) 
  Published    1976 
  Keywords    Manganesecarbonyl Derivatives, Tritertiary Phosphine, Raman Spectra, IR Spectra, FIR Spectra 
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 TEI-XML for    default:Reihe_B/31/ZNB-1976-31b-1350.pdf 
 Identifier    ZNB-1976-31b-1350 
 Volume    31