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'Tripod Ligands' in keywords
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1996 (1)
1Author    O. Laf Walter, G. Ottfried Hüttner, R. Ainer KernRequires cookie*
 Title    D a r s  
 Abstract    t e llu n g u n d C h a r a k t e r is ie r u n g v o n N (C H 2P P h 2)3, N (C H 2P P h 2)3M o (C O)3 u n d [ H N (C H 2P P h 2)3M o (C Ö) 3 ] B F 4 Preparation and Characterisation o f N (C H 2PPh-,)3, N (C H 2P P h i)3M o(C O)3 and [H N (CH 2PPh2)3M o(C O)3]BF4 The synthesis of N(CH2PPh2)3 (1) and its spectroscopic properties are reported. Reaction of N(CH2PPh2)3 with (CH3CN)3M o(CO)3 leads to N(CH 2PPh2)3M o(CO)3 (2). The cationic complex [HN(CH2PPh2)3Mo(CO)3]+ (3) is obtained by protonating the N atom of 2 with aqueous HBF4. The spectroscopic and structural properties of 2 and the cation 3 are compared. The results indicate an interaction of the ligand N atom and the Mo atom through space over more than 350 pm. It is shown from IR data that 2 
  Reference    Z. Naturforsch. 51b, 922—928 (1996); eingegangen am 18. Januar 1996 
  Published    1996 
  Keywords    Tripod Ligands, Phosphorus Ligands, Molybdenum Complexes, Crystal Structure 
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 TEI-XML for    default:Reihe_B/51/ZNB-1996-51b-0922.pdf 
 Identifier    ZNB-1996-51b-0922 
 Volume    51