| | 1 | Author
| Fritjof Schmock, Aida El-Kholi, Ulrich Müller, Kurt Dehnicke | Requires cookie* | | | Title
| Synthesis and Crystal Structure of PPh 3 Me[HS0 4 ]  | | | | Abstract
| PPh 3 Me[HS0 4 ] was prepared by the reaction of (PPh,Me)I with silver sulfate in aqueous solution. OPPh : Me and benzene being the by-products. The title compound was characterized by its IR spectrum as well as by an X-ray structure determination (1730 observed independent reflexions, R = 0.043). Crys-tal data: a = 910.4(3). b = 1587.8(4), c = 1294.2(6) pm, ß = 105.52(3)°. space group P2,/c t Z = 4. The structure consists of PPh,Me® cations and of HOSO, 0 ions that are associated via strong hydrogen bonds to dimeric centrosymmetric units. | | | |
Reference
| Z. Naturforsch. 43b, 1069—1071 (1988); eingegangen am 13. April 1988 | | | |
Published
| 1988 | | | |
Keywords
| Triphenylmethylphosphonium Hydrogensulfate, Synthesis, IR Spectra, Crystal Structure | | | |
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