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'Trifluoromethylhydroxylammonium Salts' in keywords Facet   Publication Year 1993  [X]
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1Author    Minkwitz, Hans Preut, M. Athias, Seifert, Dirk LamekRequires cookie*
 Title    Die Darstellung von Trifluormethylnitrylhexafluorometallaten CF2N (0 )H +MF6~, Trifluormethylhydroxylammoniumhexafluorometallaten CF3N H 2O H +MF6  
 Abstract    (M = As, Sb) und Kristallstruktur von CF3NH 2O H +AsF6" Preparation of Trifluoromethylnitryl-Hexafluorometallates C F 3N (0)H + M F 6~, Trifluorom ethylhydroxylamm onium -Hexafluorom etallates C F 3N H 2O H +M F 6_ (M = As, Sb) and Crystal Structure of C F 3N H 2O H +A sF6~ R olf The preparation o f C F 3N (0)H + M F6~ and C F 3N H ,O H +M F 6' (M = As, Sb) and the crystal structure o f C F 3N H 2O H +A sF 6_ are reported. C F 3N (Ö)H +M F 6~ is prepared by protonation o f C F 3N O in the superacid system H F /M F 5 (M = As, Sb). With an excess o f C F 3N O the cation C F 3N H 2O H +M F6" is formed. C F3NH-,OH+A sF 6~ crystallizes in the triclinic space group P 1 with a = 5.071(2), b = 8.297(3), c = 8.882(4)Ä, a = 90.93(4)°, ß = 95.49(4)°, y = 102.96(4)° and Z = 2. It is formed by a redox reaction between C F 3N (0) H + and excess C F 3N O. 
  Reference    Z. Naturforsch. 48b, 1241—1247 (1993); eingegangen am 23. April 1993 
  Published    1993 
  Keywords    Nitryl Salts, Trifluoromethylhydroxylammonium Salts, Preparation, Spectra, Crystal Structure 
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 TEI-XML for    default:Reihe_B/48/ZNB-1993-48b-1241.pdf 
 Identifier    ZNB-1993-48b-1241 
 Volume    48