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1997 (1)
1Author    SvitlanaR. Petrusenkoa, Joachim Sielerb, VladimirN. Kokozay3 'Requires cookie*
 Title    Direct Synthesis of Zinc and Nickel(II) Complexes with l,4-Diazabicyclo[2.2.2]octane  
 Abstract    The peculiarities of the formation of zinc and nickel(II) complexes by interaction of metal powder or metal oxide with ammonium salts (halides, nitrate, thiocyanate) were investigated in non-aqueous solutions (methanol, acetonitrile, N,N-dimethylformamide=DMF, dimethylsulf-oxide=DMSO) in presence of l,4-diazabicyclo[2.2.2]octane. The stoichiometry of the com ­ plexes was found to depend on the initial reagent ratio Ni/ZnOiNfLX and Ni/ZnO:Ten. The compounds of compositions Z n(H Ten)(H 20)(N 03)3 and Ni(HTen)(Ten)Cb were character­ ized by X-ray crystallography. Both complexes contain five-coordinate metal atoms. The zinc compound possesses monomeric molecular structure whilst the nickel complex is polymeric. 
  Reference    Z. Naturforsch. 52b, 331—336 (1997); received July 30 1996 
  Published    1997 
  Keywords    Synthesis, Zinc, Nickel(II), Triethylenediamine, X-Ray 
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 TEI-XML for    default:Reihe_B/52/ZNB-1997-52b-0331.pdf 
 Identifier    ZNB-1997-52b-0331 
 Volume    52