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'Trichlorosilyl Groups' in keywords
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1997 (1)
1Author    Bernd Schwarze, Wolfgang Milius, Wolfgang SchnickRequires cookie*
 Title    Synthese und Kristallstruktur von [(CXjSi^N^TiC^ -ein perchloriertes N-Silyl-titanamid Synthesis and Crystal Structure of [(Cl3Si)2N]2TiCl2 -a Fully Chlorinated N-Silyl Titanium Amide  
 Abstract    The chlorinated titanium amides [(Cl3Si)2N]2TiCl2 (1) and (Cl3Si)2NTiCl3 have been syn­ thesized selectively from hexachlorodisilazane lithium and TiCl4. The crystal structure of 1 was determined by single crystal X-ray methods at room temperature (P2|2j 2 |, a = 1232.4(2), b = 1265.5(2), c -1469.1(2) pm, Z = 4). The central titanium atom of 1 is bound to two nitrogen atoms and two Cl atoms and is weakly coordinated further by two Cl atoms of the trichlorosilyl groups. 
  Reference    Z. Naturforsch. 52b, 819—822 (1997); eingegangen am 1. April 1997 
  Published    1997 
  Keywords    N-Silyl Titanium Amides, Trichlorosilyl Groups, Crystal Structure, Titanium 
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 TEI-XML for    default:Reihe_B/52/ZNB-1997-52b-0819.pdf 
 Identifier    ZNB-1997-52b-0819 
 Volume    52