| | 1 | Author
| Josef Geisenberger, Jürgen Erbe, Jürgen Heidrich, Ulrich Nagel, Wolfgang Beck | Requires cookie* | | | Title
| Pseudohalogenometallverbindungen, LXV [1] Synthese von Tetrazolen und Triazolen über die 1,3-dipolare Cycloaddition an die Azid-Liganden von polymeren Cobalt(III)-und PalIadium(II)-Komplexen. Darstellung und Struktur von 5-TrichlormethyItetrazol Pseudohalogeno Metal Compounds, LXV [1] Synthesis of Tetrazoles and Triazoles via 1,3-Dipolar Cycloaddition to the Azido Ligands of Polymerie Cobalt(III) and Palladium(II) Complexes. Synthesis and Structure of 5-Trichloromethyltetrazole  | | | | Abstract
| The cycloaddition of nitriles and of dimethylacetylenedicarboxylate to the azide ligand of polymeric Schiff Base cobalt(III) and phosphine palladium(II) complexes gives the corresponding tetrazolate and triazolate complexes from which the heterocycles could be cleaved by hydrogen chloride. Usually the yields are low; if the heterocycle is soluble in ether or sublimable, yields up to 30% have been obtained. Using this method the hitherto unknown 5-trichlormethyltetrazole could be prepared which was characterized by an X-ray structural analysis. Similarly, the cyclo-addition of azido(tetraphenylporphinato)cobalt(III) with nitriles, cyclohexylisocyanide and Me0 2 CC=CC0 2 Me affords the corresponding complexes with heterocyclic ligands. The prepa-ration of tetraphenylporphyrinato(tricyanmethanido)cobalt(III), (TPP)CoN-CC(CN) 2 , is reported. | | | |
Reference
| (Z. Naturforsch. 42b, 55—64 [1987]; eingegangen am 24. Juli 1986) | | | |
Published
| 1987 | | | |
Keywords
| Tetrazoles, Triazoles, Polymerie Schiff Base Cobalt(III) Complexes, Phosphine Palladium Complexes with Azide, Tetrazolate and Triazolate Ligands | | | |
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| default:Reihe_B/42/ZNB-1987-42b-0055.pdf | | | | Identifier
| ZNB-1987-42b-0055 | | | | Volume
| 42 | |
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