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'Triazadienyl Fluoride' in keywords Facet   Publication Year 1991  [X]
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1991[X]
1Author    Gabriele Schatte, Helge WillnerRequires cookie*
 Title    Die Wechselwirkung von N 3F mit Lewis-Säuren und HF. N 3F als möglicher Vorläufer für die Synthese von N 3+-Salzen The Interaction of N 3F with Lewis-Acids and HF. N 3F as Possible Precursor for the Synthesis of N 3+ Salts  
 Abstract    Triazadienyl fluoride, N 3F, forms stable adducts with BF3 and AsF5 at low temperatures, as demonstrated by infrared measurements. The Lewis acids are bonded to the Na-atom of N 3F, as deduced from the data for 15N-isotopically enriched N 3F. The basicity of N 3F is comparable to that of ethine and ethene, according to the HF stretching frequency of the N 3F/HF complex isolated in an argon matrix. Despite the low NF bond energy (<150 kJ/mol), abstraction of the fluoride ion and formation of an N 3+ salt was not possible. The different behavior of N 3F and C1N3 towards Lewis acids is discussed. 
  Reference    Z. Naturforsch. 46b, 483—489 (1991); eingegangen am 3. September 1990 
  Published    1991 
  Keywords    Triazadienyl Fluoride, IR Spectra, Lewis Acids, Proton Affinity 
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 TEI-XML for    default:Reihe_B/46/ZNB-1991-46b-0483.pdf 
 Identifier    ZNB-1991-46b-0483 
 Volume    46