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'Transition Metals' in keywords Facet   Publication Year 1978  [X]
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1978[X]
1Author    Manfred Weidenbruch, Claude Pierrard, Helge PeselRequires cookie*
 Title    Neue Siloxanverbindungen einiger Übergangsmetalle Silicon Compounds with Strong Intramolecular Steric Interactions, VIII [1] New Siloxane Compounds of Some Transition Metals  
 Abstract    Tri-£er£-butylsiloxane compounds of transition metals are obtained by two different routes, one of these involves condensation of tri-Zer£-butylsilanol with the binary oxides V2O5, CrC>3, M0O3, and Re2Ü7, while the other proceeds via a similar reaction between the chlorides VOCl3, NbCls, TaCls, Cr02Cl2, and the silanol. The new compounds, having good thermal stability and remarkable resistence to hydrolysis, are characterized by IR, 1 H NMR, and mass spectra. 
  Reference    Z. Naturforsch. 33b, 1468—47 (1978); eingegangen am 20. September 1978 
  Published    1978 
  Keywords    Tri-ierf-butylsiloxanes, Transition Metals, Steric Hindrance, Mass Spectra 
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 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-1468.pdf 
 Identifier    ZNB-1978-33b-1468 
 Volume    33