Go toArchive
Browse byFacets
Bookbag ( 0 )
'Transannular Interaction' in keywords
Results  2 Items
Sorted by   
Section
Publication Year
1988 (1)
1981 (1)
1Author    Rolf Gleiter, Richard BartetzkoRequires cookie*
 Title    The Structures of S4N e , S3N202 and S4N3 e  
 Abstract    Part of the potential surface of S4N e has been investigated using the MNDO method. It is found that the cis-trans isomer lb is more stable by 20-30 kJ/mol than the trans-trans isomer (1 c) and the cis-cis isomer (1 a). The stability of 1 b is traced back to stabilization of the HOMO and to a Coulomb attraction. For S3N2O2 (2) the MNDO calculations favour those isomers (2a and 2b) with two sickle-like arrangements for the same reasons. For S4N3 e (3) only one isomer (3a) is favoured due to the stabilization of the HOMO. The similarity in the transannular interaction present in 1-3 and that in trithiapentalenes and related compounds is pointed out. The PE spectrum of 2 has been reinvestigated. The first five bands can be interpreted by comparison between the measured ionization potentials and the calculated (MNDO) orbital energies. 
  Reference    Z. Naturforsch. 36b, 492—497 (1981); received December 22 1980 
  Published    1981 
  Keywords    Structural Isomers, MNDO Calculations, Transannular Interactions 
  Similar Items    Find
 DEBUG INFO      
 TEI-XML for    default:Reihe_B/36/ZNB-1981-36b-0492.pdf 
 Identifier    ZNB-1981-36b-0492 
 Volume    36 
2Author    Bernhard Glaser, ErwinP. Mayer, Heinrich Nöth, Wilfried Rattay, Ulrich WietelmannRequires cookie*
 Title    Beiträge zur Chemie des Bors, 190 [1] Synthese und Molekülstruktur von 1,2-Dihydroboreten und Azadiboretidinen Contribution to the Chemistry of Boron, 190 [1] Synthesis and Molecular Structure of 1,2-Dihydrodiboretes and Azadiboretidines  
 Abstract    [2+2]-Cycloadditions of 9-Fluorenylidentetramethylpiperidinoboranes have been studied with selected olefines, acetylenes and iminoboranes. No reactions with olefines were observed. While propiolic methylester reacts exclusively at the carbonyl bond producing the oxaboretane 5, alkines such as diethylamino-alkines, cyclo-octine and phenylacetylene provide access to the'1,2-dihy-droboretenes 6, 3 and 2. Tetramethylpiperidinoiminoboranes make 1.2.4-azadiboretidines 7 available. 6a and 7a contain a folded four-membered ring as shown by X-ray structure analysis. There is only a weak 1,3-intraannular interaction due to BN-;r-bonding of the boron atoms with their exocyclic amino group. 
  Reference    Z. Naturforsch. 43b, 449—456 (1988); eingegangen am 10. Dezember 1987 
  Published    1988 
  Keywords    Reactivity of Aminomethyleneboranes, Transannular Interaction, X-Ray, 1, 2-Dihydroboret Derivatives, 1, 24-Azadiboretidine Derivatives 
  Similar Items    Find
 DEBUG INFO      
 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-0449.pdf 
 Identifier    ZNB-1988-43b-0449 
 Volume    43