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'Titanocene Complexes' in keywords Facet   Publication Year 1997  [X]
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1Author    Ralf Steudel, Monika Kustos, Andreas PrenzelRequires cookie*
 Abstract    y n t h e s is a n d S t r u c t u r e o f B i s [ d i(m e t h y lc y c lo p e n t a d ie n y l) c h lo r o -t it a n iu m ] t r is u lf id e [ (C p 2 C lT i)2S 3 ] -a R e a g e n t fo r T r is u lf id e L ig a n d T r a n s f e r R e a c t io n s [1] The dinuclear metallacycle of [Cp2Ti(/z-S2)2TiCp2] reacts with phosgene or thiophosgene to give [(CP2CITO2S3] which has been characterized by 1H and l3C NMR spectra as well as by an X-ray structure analysis. The trisulfido complex contains a helical TiSSSTi unit and may serve as an S3 transfer reagent in reactions with SCl-functional compounds. 
  Reference    (Z. Naturforsch. 52b, 79—82 [1997]; received June 18 1996) 
  Published    1997 
  Keywords    Titanocene Complexes, Polysulfide Ligands, Structure, NMR Spectra 
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 TEI-XML for    default:Reihe_B/52/ZNB-1997-52b-0079.pdf 
 Identifier    ZNB-1997-52b-0079 
 Volume    52