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1993 (1)
1Author    U. Lf Thewalt, Thomas WöhrleRequires cookie*
 Title    Titanium(IV) Fulvalene Complexes. Preparation and Structure of [CpTiPh2]-,(C10H 8)  
 Abstract    The green insoluble TiIV compound which is obtained by treating titanocene with HC1 reacts with PhLi to yield the fulvalene-bridged com pound [CpTiPh2]2(C l0H 8) 3(Ph). An X-ray struc­ ture analysis o f 3(Ph) shows, that the Ti atom s are in a trans arrangement with respect to the fulvalene group. Crystal data for 3(Ph) are as follows: C44H3gTi2, orthorhom bic, space group P 2 ,2 ,2 ,, with a = 11,3 8 5(2),/)= 14,510(2), c = 19,489(4) A, Z = 4. The crystals exhibit enan-tiomorphism. 
  Reference    Z. Naturforsch. 48b, 603 (1993); eingegangen am 28. Dezember 1992 
  Published    1993 
  Keywords    Titanium(IV) Complex, Fulvalene Ligand, Molecular Structure 
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 TEI-XML for    default:Reihe_B/48/ZNB-1993-48b-0603.pdf 
 Identifier    ZNB-1993-48b-0603 
 Volume    48