| 1 | Author
| Hk Wulff, Müller-Buschbaum | Requires cookie* | | Title
| Synthese und Kristallstruktur des Lanthan-Titanat-Tellurats LaTi  | | | Abstract
| (Ti0 2 5Te0j 5)O6 und seine Verwandtschaft mit PbSb20 6 und Sr(MnTe)06 Synthesis and Crystal Structure of the Lanthanum Titanate Tellurate LaTi(Ti0 25Te0 75) 0 6 and its Relationship to PbSb20 6 and Sr(M nTe)06 L. Single crystals of LaTi(Ti0 25T e o .75) 0 6 have been prepared by solid state reactions. X-ray investigations led to trigonal symmetry, space group C3-P3 , a = 5.141(10), c = 5.218(10) A, Z = 1. The compound is characterized by a predominantly ordered distribution of Ti4+ and Te6+. Typical features of the crystal structure are staggered layers containing edge connected T i0 6 and (Ti,Te)06 octahedra. The layers are connected by La3+ ions receiving an octahedral coordination by the surrounding oxygen ions. The relationships to the PbSb20 6 type and the recently described compound Sr(M nTe)06 are discussed. | | |
Reference
| Z. Naturforsch. 53b, 149—152 (1998); eingegangen am 25. November 1997 | | |
Published
| 1998 | | |
Keywords
| Lanthanum, Titanate, Tellurate, Crystal Structure | | |
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| default:Reihe_B/53/ZNB-1998-53b-0149.pdf | | | Identifier
| ZNB-1998-53b-0149 | | | Volume
| 53 | |
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